Home > Research > Publications & Outputs > Nuclear-driven production of renewable fuel add...

Links

Text available via DOI:

View graph of relations

Nuclear-driven production of renewable fuel additives from waste organics

Research output: Contribution to journalJournal articlepeer-review

Published

Standard

Nuclear-driven production of renewable fuel additives from waste organics. / Plant, A.G.; Kos, B.; Jazbec, A.; Snoj, L.; Najdanovic-Visak, V.; Joyce, M.J.

In: Communications Chemistry, Vol. 4, No. 1, 132, 17.09.2021.

Research output: Contribution to journalJournal articlepeer-review

Harvard

Plant, AG, Kos, B, Jazbec, A, Snoj, L, Najdanovic-Visak, V & Joyce, MJ 2021, 'Nuclear-driven production of renewable fuel additives from waste organics', Communications Chemistry, vol. 4, no. 1, 132. https://doi.org/10.1038/s42004-021-00572-5

APA

Plant, A. G., Kos, B., Jazbec, A., Snoj, L., Najdanovic-Visak, V., & Joyce, M. J. (2021). Nuclear-driven production of renewable fuel additives from waste organics. Communications Chemistry, 4(1), [132]. https://doi.org/10.1038/s42004-021-00572-5

Vancouver

Plant AG, Kos B, Jazbec A, Snoj L, Najdanovic-Visak V, Joyce MJ. Nuclear-driven production of renewable fuel additives from waste organics. Communications Chemistry. 2021 Sep 17;4(1). 132. https://doi.org/10.1038/s42004-021-00572-5

Author

Plant, A.G. ; Kos, B. ; Jazbec, A. ; Snoj, L. ; Najdanovic-Visak, V. ; Joyce, M.J. / Nuclear-driven production of renewable fuel additives from waste organics. In: Communications Chemistry. 2021 ; Vol. 4, No. 1.

Bibtex

@article{f54c2791a13345c694983b2ec918eaff,
title = "Nuclear-driven production of renewable fuel additives from waste organics",
abstract = "Non-intermittent, low-carbon energy from nuclear or biofuels is integral to many strategies to achieve Carbon Budget Reduction targets. However, nuclear plants have high, upfront costs and biodiesel manufacture produces waste glycerol with few secondary uses. Combining these technologies, to precipitate valuable feedstocks from waste glycerol using ionizing radiation, could diversify nuclear energy use whilst valorizing biodiesel waste. Here, we demonstrate solketal (2,2-dimethyl-1,3-dioxolane-4-yl) and acetol (1-hydroxypropan-2-one) production is enhanced in selected aqueous glycerol-acetone mixtures with γ radiation with yields of 1.5 ± 0.2 µmol J−1 and 1.8 ± 0.2 µmol J−1, respectively. This is consistent with the generation of either the stabilized, protonated glycerol cation (CH2OH-CHOH-CH2OH2+) from the direct action of glycerol, or the hydronium species, H3O+, via water radiolysis, and their role in the subsequent acid-catalyzed mechanisms for acetol and solketal production. Scaled to a hypothetically compatible range of nuclear facilities in Europe (i.e., contemporary Pressurised Water Reactor designs or spent nuclear fuel stores), we estimate annual solketal production at approximately (1.0 ± 0.1) × 104 t year−1. Given a forecast increase of 5% to 20% v/v% in the renewable proportion of commercial petroleum blends by 2030, nuclear-driven, biomass-derived solketal could contribute towards net-zero emissions targets, combining low-carbon co-generation and co-production. {\textcopyright} 2021, The Author(s).",
author = "A.G. Plant and B. Kos and A. Jazbec and L. Snoj and V. Najdanovic-Visak and M.J. Joyce",
year = "2021",
month = sep,
day = "17",
doi = "10.1038/s42004-021-00572-5",
language = "English",
volume = "4",
journal = "Communications Chemistry",
issn = "2399-3669",
publisher = "Nature Publishing Group",
number = "1",

}

RIS

TY - JOUR

T1 - Nuclear-driven production of renewable fuel additives from waste organics

AU - Plant, A.G.

AU - Kos, B.

AU - Jazbec, A.

AU - Snoj, L.

AU - Najdanovic-Visak, V.

AU - Joyce, M.J.

PY - 2021/9/17

Y1 - 2021/9/17

N2 - Non-intermittent, low-carbon energy from nuclear or biofuels is integral to many strategies to achieve Carbon Budget Reduction targets. However, nuclear plants have high, upfront costs and biodiesel manufacture produces waste glycerol with few secondary uses. Combining these technologies, to precipitate valuable feedstocks from waste glycerol using ionizing radiation, could diversify nuclear energy use whilst valorizing biodiesel waste. Here, we demonstrate solketal (2,2-dimethyl-1,3-dioxolane-4-yl) and acetol (1-hydroxypropan-2-one) production is enhanced in selected aqueous glycerol-acetone mixtures with γ radiation with yields of 1.5 ± 0.2 µmol J−1 and 1.8 ± 0.2 µmol J−1, respectively. This is consistent with the generation of either the stabilized, protonated glycerol cation (CH2OH-CHOH-CH2OH2+) from the direct action of glycerol, or the hydronium species, H3O+, via water radiolysis, and their role in the subsequent acid-catalyzed mechanisms for acetol and solketal production. Scaled to a hypothetically compatible range of nuclear facilities in Europe (i.e., contemporary Pressurised Water Reactor designs or spent nuclear fuel stores), we estimate annual solketal production at approximately (1.0 ± 0.1) × 104 t year−1. Given a forecast increase of 5% to 20% v/v% in the renewable proportion of commercial petroleum blends by 2030, nuclear-driven, biomass-derived solketal could contribute towards net-zero emissions targets, combining low-carbon co-generation and co-production. © 2021, The Author(s).

AB - Non-intermittent, low-carbon energy from nuclear or biofuels is integral to many strategies to achieve Carbon Budget Reduction targets. However, nuclear plants have high, upfront costs and biodiesel manufacture produces waste glycerol with few secondary uses. Combining these technologies, to precipitate valuable feedstocks from waste glycerol using ionizing radiation, could diversify nuclear energy use whilst valorizing biodiesel waste. Here, we demonstrate solketal (2,2-dimethyl-1,3-dioxolane-4-yl) and acetol (1-hydroxypropan-2-one) production is enhanced in selected aqueous glycerol-acetone mixtures with γ radiation with yields of 1.5 ± 0.2 µmol J−1 and 1.8 ± 0.2 µmol J−1, respectively. This is consistent with the generation of either the stabilized, protonated glycerol cation (CH2OH-CHOH-CH2OH2+) from the direct action of glycerol, or the hydronium species, H3O+, via water radiolysis, and their role in the subsequent acid-catalyzed mechanisms for acetol and solketal production. Scaled to a hypothetically compatible range of nuclear facilities in Europe (i.e., contemporary Pressurised Water Reactor designs or spent nuclear fuel stores), we estimate annual solketal production at approximately (1.0 ± 0.1) × 104 t year−1. Given a forecast increase of 5% to 20% v/v% in the renewable proportion of commercial petroleum blends by 2030, nuclear-driven, biomass-derived solketal could contribute towards net-zero emissions targets, combining low-carbon co-generation and co-production. © 2021, The Author(s).

U2 - 10.1038/s42004-021-00572-5

DO - 10.1038/s42004-021-00572-5

M3 - Journal article

VL - 4

JO - Communications Chemistry

JF - Communications Chemistry

SN - 2399-3669

IS - 1

M1 - 132

ER -