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Orange II adsorption on palygorskites modified with alkyl trimethylammonium and dialkyl dimethylammonium bromide - An isothermal and kinetic study

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Orange II adsorption on palygorskites modified with alkyl trimethylammonium and dialkyl dimethylammonium bromide - An isothermal and kinetic study. / Sarkar, B; Xi, YF; Megharaj, M et al.
In: Applied Clay Science, Vol. 51, No. 3, 28.02.2011, p. 370-374.

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Sarkar B, Xi YF, Megharaj M, Naidu R. Orange II adsorption on palygorskites modified with alkyl trimethylammonium and dialkyl dimethylammonium bromide - An isothermal and kinetic study. Applied Clay Science. 2011 Feb 28;51(3):370-374. Epub 2010 Dec 13. doi: 10.1016/j.clay.2010.11.032

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@article{194506113f1a46cb9dbb5a1c7a3830e3,
title = "Orange II adsorption on palygorskites modified with alkyl trimethylammonium and dialkyl dimethylammonium bromide - An isothermal and kinetic study",
abstract = "We modified an Australian palygorskite with octadecyl trimethylammonium bromide (ODTMA) and dioctadecyl dimethylammonium bromide (DODMA) at different concentrations, and assessed these organo-palygorskites for adsorption of the anionic dye orange II. The surface and pore structure of the modified palygorskites were analysed by nitrogen adsorption. Orange II adsorption on palygorskites modified with DODMA and ODTMA quantity equivalent to twice the cation exchange capacity (CEC) of palygorskite was as high as 92 and 88 mg/g at 25 °C. The ODTMA and DODMA modified palygorskites did not differ greatly in their adsorption capacities. We also studied the influence of various experimental parameters such as the amount of adsorbent, mixing time, temperatures and pH values on the adsorption of orange II by the organo-palygorskites. Both electrostatic attraction as well as van der Waals interaction controlled the adsorption over the whole range of concentrations. This study demonstrates the potential application of organo-palygorskites for the remediation of anionic dyes from wastewater.",
keywords = "Palygorskite, Octadecyl trimethylammonium, Dioctadecyl dimethylammonium, Orange II, Dye, Adsorption",
author = "B Sarkar and YF Xi and M Megharaj and R Naidu",
year = "2011",
month = feb,
day = "28",
doi = "10.1016/j.clay.2010.11.032",
language = "English",
volume = "51",
pages = "370--374",
journal = "Applied Clay Science",
issn = "0169-1317",
publisher = "Elsevier BV",
number = "3",

}

RIS

TY - JOUR

T1 - Orange II adsorption on palygorskites modified with alkyl trimethylammonium and dialkyl dimethylammonium bromide - An isothermal and kinetic study

AU - Sarkar, B

AU - Xi, YF

AU - Megharaj, M

AU - Naidu, R

PY - 2011/2/28

Y1 - 2011/2/28

N2 - We modified an Australian palygorskite with octadecyl trimethylammonium bromide (ODTMA) and dioctadecyl dimethylammonium bromide (DODMA) at different concentrations, and assessed these organo-palygorskites for adsorption of the anionic dye orange II. The surface and pore structure of the modified palygorskites were analysed by nitrogen adsorption. Orange II adsorption on palygorskites modified with DODMA and ODTMA quantity equivalent to twice the cation exchange capacity (CEC) of palygorskite was as high as 92 and 88 mg/g at 25 °C. The ODTMA and DODMA modified palygorskites did not differ greatly in their adsorption capacities. We also studied the influence of various experimental parameters such as the amount of adsorbent, mixing time, temperatures and pH values on the adsorption of orange II by the organo-palygorskites. Both electrostatic attraction as well as van der Waals interaction controlled the adsorption over the whole range of concentrations. This study demonstrates the potential application of organo-palygorskites for the remediation of anionic dyes from wastewater.

AB - We modified an Australian palygorskite with octadecyl trimethylammonium bromide (ODTMA) and dioctadecyl dimethylammonium bromide (DODMA) at different concentrations, and assessed these organo-palygorskites for adsorption of the anionic dye orange II. The surface and pore structure of the modified palygorskites were analysed by nitrogen adsorption. Orange II adsorption on palygorskites modified with DODMA and ODTMA quantity equivalent to twice the cation exchange capacity (CEC) of palygorskite was as high as 92 and 88 mg/g at 25 °C. The ODTMA and DODMA modified palygorskites did not differ greatly in their adsorption capacities. We also studied the influence of various experimental parameters such as the amount of adsorbent, mixing time, temperatures and pH values on the adsorption of orange II by the organo-palygorskites. Both electrostatic attraction as well as van der Waals interaction controlled the adsorption over the whole range of concentrations. This study demonstrates the potential application of organo-palygorskites for the remediation of anionic dyes from wastewater.

KW - Palygorskite

KW - Octadecyl trimethylammonium

KW - Dioctadecyl dimethylammonium

KW - Orange II

KW - Dye

KW - Adsorption

UR - http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000287893000024&KeyUID=WOS:000287893000024

U2 - 10.1016/j.clay.2010.11.032

DO - 10.1016/j.clay.2010.11.032

M3 - Journal article

VL - 51

SP - 370

EP - 374

JO - Applied Clay Science

JF - Applied Clay Science

SN - 0169-1317

IS - 3

ER -