Final published version
Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Organochlorine pesticides (OCPs) in the Indus River catchment area, Pakistan
T2 - status, soil–air exchange and black carbon mediated distribution
AU - Bajwa, Anam
AU - Ali, Usman
AU - Mahmood, Adeel
AU - Chaudhry, Muhammad Jamshed Iqbal
AU - Syed, Jabir Hussain
AU - Li, Jun
AU - Zhang, Gan
AU - Jones, Kevin Christopher
AU - Malik, Riffat Naseem
PY - 2016/6
Y1 - 2016/6
N2 - Organochlorine pesticides (OCPs) were investigated in passive air and soil samples from the catchment area of the Indus River, Pakistan. ∑15OCPs ranged between 0.68 and 13.47 ng g−1 in soil and 375.1–1975 pg mˉ3 in air. HCHs and DDTs were more prevalent in soil and air compartments. Composition profile indicated that β-HCH and p,p'-DDE were the dominant of all metabolites among HCHs and DDTs respectively. Moreover, fBC and fTOC were assessed and evaluated their potential role in the distribution status of OCPs. The fTOC and fBC ranged between 0.77 and 2.43 and 0.04–0.30% respectively in soil. Regression analysis showed the strong influence of fBC than fTOC on the distribution of OCPs in the Indus River catchment area soil. Equilibrium status was observed for β-HCH, δ-HCH, p,p'-DDD, o,p'-DDT, TC, HCB and Heptachlor with ff ranged between 0.3 and 0.59 while assessing the soil–air exchange of OCPs.
AB - Organochlorine pesticides (OCPs) were investigated in passive air and soil samples from the catchment area of the Indus River, Pakistan. ∑15OCPs ranged between 0.68 and 13.47 ng g−1 in soil and 375.1–1975 pg mˉ3 in air. HCHs and DDTs were more prevalent in soil and air compartments. Composition profile indicated that β-HCH and p,p'-DDE were the dominant of all metabolites among HCHs and DDTs respectively. Moreover, fBC and fTOC were assessed and evaluated their potential role in the distribution status of OCPs. The fTOC and fBC ranged between 0.77 and 2.43 and 0.04–0.30% respectively in soil. Regression analysis showed the strong influence of fBC than fTOC on the distribution of OCPs in the Indus River catchment area soil. Equilibrium status was observed for β-HCH, δ-HCH, p,p'-DDD, o,p'-DDT, TC, HCB and Heptachlor with ff ranged between 0.3 and 0.59 while assessing the soil–air exchange of OCPs.
KW - Black carbon
KW - Soil–air exchange
KW - OCPs
KW - Adsorption
KW - Total organic carbon
KW - Indus River
KW - Pakistan
U2 - 10.1016/j.chemosphere.2016.01.024
DO - 10.1016/j.chemosphere.2016.01.024
M3 - Journal article
VL - 152
SP - 292
EP - 300
JO - Chemosphere
JF - Chemosphere
SN - 0045-6535
ER -