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Oxide-supported metal catalysts for anaerobic NAD+ regeneration with concurrent hydrogen production

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Oxide-supported metal catalysts for anaerobic NAD+ regeneration with concurrent hydrogen production. / Li, Jianwei; Burnett, Joseph; Martinez Macias, Claudia et al.
In: Chinese Chemical Letters, Vol. 35, No. 2, 108737, 29.02.2024.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Li, J, Burnett, J, Martinez Macias, C, Howe, RF & Wang, X 2024, 'Oxide-supported metal catalysts for anaerobic NAD+ regeneration with concurrent hydrogen production', Chinese Chemical Letters, vol. 35, no. 2, 108737. https://doi.org/10.1016/j.cclet.2023.108737

APA

Li, J., Burnett, J., Martinez Macias, C., Howe, R. F., & Wang, X. (2024). Oxide-supported metal catalysts for anaerobic NAD+ regeneration with concurrent hydrogen production. Chinese Chemical Letters, 35(2), Article 108737. https://doi.org/10.1016/j.cclet.2023.108737

Vancouver

Li J, Burnett J, Martinez Macias C, Howe RF, Wang X. Oxide-supported metal catalysts for anaerobic NAD+ regeneration with concurrent hydrogen production. Chinese Chemical Letters. 2024 Feb 29;35(2):108737. Epub 2023 Jun 28. doi: 10.1016/j.cclet.2023.108737

Author

Li, Jianwei ; Burnett, Joseph ; Martinez Macias, Claudia et al. / Oxide-supported metal catalysts for anaerobic NAD+ regeneration with concurrent hydrogen production. In: Chinese Chemical Letters. 2024 ; Vol. 35, No. 2.

Bibtex

@article{ecd2d07a4aa34f599270fa6664638f04,
title = "Oxide-supported metal catalysts for anaerobic NAD+ regeneration with concurrent hydrogen production",
abstract = "We report SiO2-supported monometallic Pt, Pd, Au, Ni, Cu and Co catalysts for protondriven NAD+ regeneration, co-producing H2. All metals are fully selective to NAD+ where the order of turnover frequencies (Pt >> Pd > Cu > Au, Ni and Co) coincides with those otherwise observed in electrochemical hydrogen evolution reactions. This has revealed that NADH is capable of converting the metal sites into a “cathode” without an external potential and the NADH to NAD+ reaction involves transferring electron and hydrogen atom separately. Electron-deficient Ptδ+ (on CeO2) enhances TOF and the heterogeneous Pt/CeO2 catalyst is recyclable without losing any activity/selectivity.",
keywords = "Heterogeneous catalyst, Hydrogen binding energy, Hydrogen production, Hydrogenase mimic, NAD regeneration",
author = "Jianwei Li and Joseph Burnett and {Martinez Macias}, Claudia and Howe, {Russell F.} and Xiaodong Wang",
year = "2024",
month = feb,
day = "29",
doi = "10.1016/j.cclet.2023.108737",
language = "English",
volume = "35",
journal = "Chinese Chemical Letters",
issn = "1001-8417",
publisher = "Elsevier",
number = "2",

}

RIS

TY - JOUR

T1 - Oxide-supported metal catalysts for anaerobic NAD+ regeneration with concurrent hydrogen production

AU - Li, Jianwei

AU - Burnett, Joseph

AU - Martinez Macias, Claudia

AU - Howe, Russell F.

AU - Wang, Xiaodong

PY - 2024/2/29

Y1 - 2024/2/29

N2 - We report SiO2-supported monometallic Pt, Pd, Au, Ni, Cu and Co catalysts for protondriven NAD+ regeneration, co-producing H2. All metals are fully selective to NAD+ where the order of turnover frequencies (Pt >> Pd > Cu > Au, Ni and Co) coincides with those otherwise observed in electrochemical hydrogen evolution reactions. This has revealed that NADH is capable of converting the metal sites into a “cathode” without an external potential and the NADH to NAD+ reaction involves transferring electron and hydrogen atom separately. Electron-deficient Ptδ+ (on CeO2) enhances TOF and the heterogeneous Pt/CeO2 catalyst is recyclable without losing any activity/selectivity.

AB - We report SiO2-supported monometallic Pt, Pd, Au, Ni, Cu and Co catalysts for protondriven NAD+ regeneration, co-producing H2. All metals are fully selective to NAD+ where the order of turnover frequencies (Pt >> Pd > Cu > Au, Ni and Co) coincides with those otherwise observed in electrochemical hydrogen evolution reactions. This has revealed that NADH is capable of converting the metal sites into a “cathode” without an external potential and the NADH to NAD+ reaction involves transferring electron and hydrogen atom separately. Electron-deficient Ptδ+ (on CeO2) enhances TOF and the heterogeneous Pt/CeO2 catalyst is recyclable without losing any activity/selectivity.

KW - Heterogeneous catalyst

KW - Hydrogen binding energy

KW - Hydrogen production

KW - Hydrogenase mimic

KW - NAD regeneration

U2 - 10.1016/j.cclet.2023.108737

DO - 10.1016/j.cclet.2023.108737

M3 - Journal article

VL - 35

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

SN - 1001-8417

IS - 2

M1 - 108737

ER -