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Palladacycles as precatalysts in Heck and cross-coupling reactions

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Published
  • Maria Munoz-Herranz
  • Belén Martín-Matute
  • Carolina Fernández-Rivas
  • Diego J. Cárdenas
  • Antonio M. Echavarren
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<mark>Journal publication date</mark>8/06/2001
<mark>Journal</mark>Advanced Synthesis & Catalysis
Issue number4
Volume343
Number of pages5
Pages (from-to)338-342
Publication StatusPublished
<mark>Original language</mark>English

Abstract

A variety of palladacycles are shown to catalyze Heck alkenylations with similar efficiencies. The new oxapalladacycle 1 was shown to insert and transmetalate under mild conditions with n-butyl acrylate and vinyltributylstannane, respectively. This palladacycle acts as an active (pre)catalyst for cross-coupling and Heck reactions.