Home > Research > Publications & Outputs > Parallel Kinetic Resolution of Intramolecular F...

Links

Text available via DOI:

View graph of relations

Parallel Kinetic Resolution of Intramolecular Furan Diels-Alder Cycloadducts via Asymmetric Hydroboration

Research output: Contribution to journalJournal articlepeer-review

Published

Standard

Parallel Kinetic Resolution of Intramolecular Furan Diels-Alder Cycloadducts via Asymmetric Hydroboration. / Fulgheri, T.; Cornwall, P.; Turner, A.R.; Sweeney, J.B.; Gill, D.M.

In: European Journal of Organic Chemistry, Vol. 2019, No. 43, 24.11.2019, p. 7223-7227.

Research output: Contribution to journalJournal articlepeer-review

Harvard

Fulgheri, T, Cornwall, P, Turner, AR, Sweeney, JB & Gill, DM 2019, 'Parallel Kinetic Resolution of Intramolecular Furan Diels-Alder Cycloadducts via Asymmetric Hydroboration', European Journal of Organic Chemistry, vol. 2019, no. 43, pp. 7223-7227. https://doi.org/10.1002/ejoc.201901407

APA

Fulgheri, T., Cornwall, P., Turner, A. R., Sweeney, J. B., & Gill, D. M. (2019). Parallel Kinetic Resolution of Intramolecular Furan Diels-Alder Cycloadducts via Asymmetric Hydroboration. European Journal of Organic Chemistry, 2019(43), 7223-7227. https://doi.org/10.1002/ejoc.201901407

Vancouver

Fulgheri T, Cornwall P, Turner AR, Sweeney JB, Gill DM. Parallel Kinetic Resolution of Intramolecular Furan Diels-Alder Cycloadducts via Asymmetric Hydroboration. European Journal of Organic Chemistry. 2019 Nov 24;2019(43):7223-7227. https://doi.org/10.1002/ejoc.201901407

Author

Fulgheri, T. ; Cornwall, P. ; Turner, A.R. ; Sweeney, J.B. ; Gill, D.M. / Parallel Kinetic Resolution of Intramolecular Furan Diels-Alder Cycloadducts via Asymmetric Hydroboration. In: European Journal of Organic Chemistry. 2019 ; Vol. 2019, No. 43. pp. 7223-7227.

Bibtex

@article{795fa2bd4dbd4c1f880b6b98aa5109ff,
title = "Parallel Kinetic Resolution of Intramolecular Furan Diels-Alder Cycloadducts via Asymmetric Hydroboration",
abstract = "Simple, parallel and dynamic: asymmetric hydroboration reactions of racemic intramolecular Diels‐Alder furan (IMDAF) cycloadducts give regiodivergent outcomes in which simple, parallel and dynamic kinetic resolutions of the substrate enantiomers may be observed.We report parallel kinetic resolution of intramolecular Diels‐Alder cycloadducts, where up to five stereocentres are defined using asymmetric hydroboration as the enantiodiscriminating reaction, and reveal evidence for dynamic kinetic resolution based on a reversible cycloaddition.",
keywords = "Cycloaddition, Enantioselectivity, Hydroboration, Kinetic resolution, Regioselectivity",
author = "T. Fulgheri and P. Cornwall and A.R. Turner and J.B. Sweeney and D.M. Gill",
year = "2019",
month = nov,
day = "24",
doi = "10.1002/ejoc.201901407",
language = "English",
volume = "2019",
pages = "7223--7227",
journal = "European Journal of Organic Chemistry",
issn = "1434-193X",
publisher = "Wiley-VCH Verlag",
number = "43",

}

RIS

TY - JOUR

T1 - Parallel Kinetic Resolution of Intramolecular Furan Diels-Alder Cycloadducts via Asymmetric Hydroboration

AU - Fulgheri, T.

AU - Cornwall, P.

AU - Turner, A.R.

AU - Sweeney, J.B.

AU - Gill, D.M.

PY - 2019/11/24

Y1 - 2019/11/24

N2 - Simple, parallel and dynamic: asymmetric hydroboration reactions of racemic intramolecular Diels‐Alder furan (IMDAF) cycloadducts give regiodivergent outcomes in which simple, parallel and dynamic kinetic resolutions of the substrate enantiomers may be observed.We report parallel kinetic resolution of intramolecular Diels‐Alder cycloadducts, where up to five stereocentres are defined using asymmetric hydroboration as the enantiodiscriminating reaction, and reveal evidence for dynamic kinetic resolution based on a reversible cycloaddition.

AB - Simple, parallel and dynamic: asymmetric hydroboration reactions of racemic intramolecular Diels‐Alder furan (IMDAF) cycloadducts give regiodivergent outcomes in which simple, parallel and dynamic kinetic resolutions of the substrate enantiomers may be observed.We report parallel kinetic resolution of intramolecular Diels‐Alder cycloadducts, where up to five stereocentres are defined using asymmetric hydroboration as the enantiodiscriminating reaction, and reveal evidence for dynamic kinetic resolution based on a reversible cycloaddition.

KW - Cycloaddition

KW - Enantioselectivity

KW - Hydroboration

KW - Kinetic resolution

KW - Regioselectivity

U2 - 10.1002/ejoc.201901407

DO - 10.1002/ejoc.201901407

M3 - Journal article

VL - 2019

SP - 7223

EP - 7227

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

SN - 1434-193X

IS - 43

ER -