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    Rights statement: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/jacs.1c05184

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Photoluminescence of Pentavalent Uranyl Amide Complexes

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Published

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Photoluminescence of Pentavalent Uranyl Amide Complexes. / Ortu, Fabrizio; Randall, Simon; Moulding, David et al.
In: Journal of the American Chemical Society, Vol. 143, No. 33, 13194, 13.08.2021, p. 13184–13194.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Ortu, F, Randall, S, Moulding, D, Woodward, A, Kerridge, A, Meyer, K, La Pierre, HS & Natrajan, LS 2021, 'Photoluminescence of Pentavalent Uranyl Amide Complexes', Journal of the American Chemical Society, vol. 143, no. 33, 13194, pp. 13184–13194. https://doi.org/10.1021/jacs.1c05184

APA

Ortu, F., Randall, S., Moulding, D., Woodward, A., Kerridge, A., Meyer, K., La Pierre, H. S., & Natrajan, L. S. (2021). Photoluminescence of Pentavalent Uranyl Amide Complexes. Journal of the American Chemical Society, 143(33), 13184–13194. Article 13194. https://doi.org/10.1021/jacs.1c05184

Vancouver

Ortu F, Randall S, Moulding D, Woodward A, Kerridge A, Meyer K et al. Photoluminescence of Pentavalent Uranyl Amide Complexes. Journal of the American Chemical Society. 2021 Aug 13;143(33):13184–13194. 13194. doi: 10.1021/jacs.1c05184

Author

Ortu, Fabrizio ; Randall, Simon ; Moulding, David et al. / Photoluminescence of Pentavalent Uranyl Amide Complexes. In: Journal of the American Chemical Society. 2021 ; Vol. 143, No. 33. pp. 13184–13194.

Bibtex

@article{327ce0653f6b4979b8e0a9064d2a24dc,
title = "Photoluminescence of Pentavalent Uranyl Amide Complexes",
abstract = "Pentavalent uranyl species are crucial intermediates in transformations that play a key role for the nuclear industry and have recently been demonstrated to persist in reducing biotic and abiotic aqueous environments. However, due to the inherent instability of pentavalent uranyl, little is known about its electronic structure. Herein, we report the synthesis and characterization of a series of monomeric and dimeric, pentavalent uranyl amide complexes. These synthetic efforts enable the acquisition of emission spectra of well-defined pentavalent uranyl complexes using photoluminescence techniques, which establish a unique signature to characterize its electronic structure and, potentially, its role in biological and engineered environments via emission spectroscopy.",
keywords = "Crystals, Energy, Vinyl, Nuclear magnetic resonance spectroscopy, Cations",
author = "Fabrizio Ortu and Simon Randall and David Moulding and Adam Woodward and Andrew Kerridge and Karsten Meyer and {La Pierre}, {Henry S.} and Natrajan, {Louise S.}",
note = "This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright {\textcopyright} American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/jacs.1c05184",
year = "2021",
month = aug,
day = "13",
doi = "10.1021/jacs.1c05184",
language = "English",
volume = "143",
pages = "13184–13194",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "AMER CHEMICAL SOC",
number = "33",

}

RIS

TY - JOUR

T1 - Photoluminescence of Pentavalent Uranyl Amide Complexes

AU - Ortu, Fabrizio

AU - Randall, Simon

AU - Moulding, David

AU - Woodward, Adam

AU - Kerridge, Andrew

AU - Meyer, Karsten

AU - La Pierre, Henry S.

AU - Natrajan, Louise S.

N1 - This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/jacs.1c05184

PY - 2021/8/13

Y1 - 2021/8/13

N2 - Pentavalent uranyl species are crucial intermediates in transformations that play a key role for the nuclear industry and have recently been demonstrated to persist in reducing biotic and abiotic aqueous environments. However, due to the inherent instability of pentavalent uranyl, little is known about its electronic structure. Herein, we report the synthesis and characterization of a series of monomeric and dimeric, pentavalent uranyl amide complexes. These synthetic efforts enable the acquisition of emission spectra of well-defined pentavalent uranyl complexes using photoluminescence techniques, which establish a unique signature to characterize its electronic structure and, potentially, its role in biological and engineered environments via emission spectroscopy.

AB - Pentavalent uranyl species are crucial intermediates in transformations that play a key role for the nuclear industry and have recently been demonstrated to persist in reducing biotic and abiotic aqueous environments. However, due to the inherent instability of pentavalent uranyl, little is known about its electronic structure. Herein, we report the synthesis and characterization of a series of monomeric and dimeric, pentavalent uranyl amide complexes. These synthetic efforts enable the acquisition of emission spectra of well-defined pentavalent uranyl complexes using photoluminescence techniques, which establish a unique signature to characterize its electronic structure and, potentially, its role in biological and engineered environments via emission spectroscopy.

KW - Crystals

KW - Energy

KW - Vinyl

KW - Nuclear magnetic resonance spectroscopy

KW - Cations

U2 - 10.1021/jacs.1c05184

DO - 10.1021/jacs.1c05184

M3 - Journal article

VL - 143

SP - 13184

EP - 13194

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 33

M1 - 13194

ER -