Final published version
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Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Polynuclear ampyrone based 3d coordination clusters
AU - Sampani, Stavroula I.
AU - Loukopoulos, Edward
AU - Azam, Mohammad
AU - Griffiths, Kieran
AU - Abdul-Sada, Alaa
AU - Tizzard, Graham
AU - Coles, Simon
AU - Escuer, Albert
AU - Tsipis, Athanassios
AU - Kostakis, George E.
PY - 2018/3/14
Y1 - 2018/3/14
N2 - The use of the monoanionic Schiff base ligand (E)-4-(2-hydroxybenzylideneamino)-2,3-dimethyl-1-phenyl-1,2-dihydropyrazol-5-one in transition (Co, Ni and Cu) coordination chemistry yields mono-, tetra- and pentanuclear coordination clusters (CCs) with different structural motifs. An organic transformation occurs in the ligand in the Cu compound for which theoretical studies are presented. Solution studies, topological issues and magnetic studies are discussed. The present results demonstrate the richness of the coordination chemistry of this monoprotic organic ligand, which promotes the formation of high-nuclearity CCs.
AB - The use of the monoanionic Schiff base ligand (E)-4-(2-hydroxybenzylideneamino)-2,3-dimethyl-1-phenyl-1,2-dihydropyrazol-5-one in transition (Co, Ni and Cu) coordination chemistry yields mono-, tetra- and pentanuclear coordination clusters (CCs) with different structural motifs. An organic transformation occurs in the ligand in the Cu compound for which theoretical studies are presented. Solution studies, topological issues and magnetic studies are discussed. The present results demonstrate the richness of the coordination chemistry of this monoprotic organic ligand, which promotes the formation of high-nuclearity CCs.
U2 - 10.1039/c7ce02093g
DO - 10.1039/c7ce02093g
M3 - Journal article
AN - SCOPUS:85042925320
VL - 20
SP - 1411
EP - 1421
JO - CrystEngComm
JF - CrystEngComm
SN - 1466-8033
IS - 10
ER -