Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Preparation of Ru(CO)(diene)2 complexes by electron beam evaporation of ruthenium.
AU - Cox, David
AU - Roulet, Raymond
PY - 1984/8/8
Y1 - 1984/8/8
N2 - Ru-atoms (0.5–1.5 g) have been generated by electron bombardment and, in separate experiments, were co-condensed at 7 K with excess of 2,3-dimethylbutadiene or 1,3- or 1,4-cyclohexadiene. The complexes Ru(CO)(η4-C6H10)2 (1) and Ru(CO)(η4-C6H8)2 (2), respectively, have been isolated in 25–30% yields on warming the condensate under CO.
AB - Ru-atoms (0.5–1.5 g) have been generated by electron bombardment and, in separate experiments, were co-condensed at 7 K with excess of 2,3-dimethylbutadiene or 1,3- or 1,4-cyclohexadiene. The complexes Ru(CO)(η4-C6H10)2 (1) and Ru(CO)(η4-C6H8)2 (2), respectively, have been isolated in 25–30% yields on warming the condensate under CO.
U2 - 10.1002/hlca.19840670522
DO - 10.1002/hlca.19840670522
M3 - Journal article
VL - 67
SP - 1365
EP - 1367
JO - Helvetica Chimica Acta
JF - Helvetica Chimica Acta
SN - 1522-2675
IS - 5
ER -