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Pretzelanes, [1]rotaxanes and molecular figures-of-eight – crossing the bridge from fundamentals to functional applications

Research output: Contribution to Journal/MagazineLiterature reviewpeer-review

E-pub ahead of print
<mark>Journal publication date</mark>12/02/2025
<mark>Journal</mark>Organic and Biomolecular Chemistry
Publication StatusE-pub ahead of print
Early online date12/02/25
<mark>Original language</mark>English

Abstract

There are myriad [2]catenanes and [2]rotaxanes that consist of two interlocked molecular components. On occasion, supramolecular chemists prepare interlocked molecules where there are covalent linkages between the interlocked molecular components. In this review progress on pretzelanes ([1]catenanes), [1]rotaxanes and molecular figures-of-eight is surveyed. Particular attention is paid to the application of such molecules, especially where the interlocked structure and/or the covalent linkage(s) play a key functional role.