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Pronounced electrochemical amphotericity of a fused donor-acceptor compound: A planar merge of TTF with a TCNQ-Ttype bithienoquinoxaline

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Published
  • X. Guégano
  • A.L. Kanibolotsky
  • C. Blum
  • S.F.L. Mertens
  • S.-X. Liu
  • A. Neels
  • H. Hagemann
  • P.J. Skabara
  • S. Leutwyler
  • T. Wandlowski
  • A. Hauser
  • S. Decurtins
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<mark>Journal publication date</mark>2009
<mark>Journal</mark>Chemistry - A European Journal
Issue number1
Volume15
Number of pages4
Pages (from-to)63-66
Publication StatusPublished
<mark>Original language</mark>English

Abstract

Narrowing the gap: A compactly fused π‐conjugated molecule combines a high‐lying HOMO with a low‐lying LUMO (Eox−Ered=0.52 eV) and a fairly low‐lying LUMO+1 on the bridging unit, giving rise to strong optical charge‐transfer transitions. A facile electron transfer has been observed by EPR and NMR spectroscopies.