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Protonated open and half-open ruthenocenes exhibiting agostic interactions with C-H bond rupture involved in the most facile dynamic process

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Protonated open and half-open ruthenocenes exhibiting agostic interactions with C-H bond rupture involved in the most facile dynamic process. / Cox, David; Roulet, Raymond.
In: Chemical Communications, No. 3, 1989, p. 175-177.

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@article{14f7536f1f3940d8ac1d54f7634da868,
title = "Protonated open and half-open ruthenocenes exhibiting agostic interactions with C-H bond rupture involved in the most facile dynamic process",
abstract = "The cations [Ru(η5-C7H11)2H]+(1), [Ru(η5-C5H5)(η5-C7H11)H]+(2), and [Ru(η5-C7H11)H]+(3) have provided quantitative evidence for the existence of a class of complexes in which rupture of the C–H component of a C–H–M agostic interaction is involved in the lowest energy fluxional processes.",
author = "David Cox and Raymond Roulet",
year = "1989",
doi = "10.1039/c39890000175",
language = "English",
pages = "175--177",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "3",

}

RIS

TY - JOUR

T1 - Protonated open and half-open ruthenocenes exhibiting agostic interactions with C-H bond rupture involved in the most facile dynamic process

AU - Cox, David

AU - Roulet, Raymond

PY - 1989

Y1 - 1989

N2 - The cations [Ru(η5-C7H11)2H]+(1), [Ru(η5-C5H5)(η5-C7H11)H]+(2), and [Ru(η5-C7H11)H]+(3) have provided quantitative evidence for the existence of a class of complexes in which rupture of the C–H component of a C–H–M agostic interaction is involved in the lowest energy fluxional processes.

AB - The cations [Ru(η5-C7H11)2H]+(1), [Ru(η5-C5H5)(η5-C7H11)H]+(2), and [Ru(η5-C7H11)H]+(3) have provided quantitative evidence for the existence of a class of complexes in which rupture of the C–H component of a C–H–M agostic interaction is involved in the lowest energy fluxional processes.

U2 - 10.1039/c39890000175

DO - 10.1039/c39890000175

M3 - Journal article

SP - 175

EP - 177

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 3

ER -