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Quantitative measurement of Q(3) species in silicate and borosilicate glasses using Raman spectroscopy

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Quantitative measurement of Q(3) species in silicate and borosilicate glasses using Raman spectroscopy. / Parkinson, B. G.; Holland, D.; Smith, Mark E. et al.
In: Journal of Non-Crystalline Solids, Vol. 354, No. 17, 01.04.2008, p. 1936-1942.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Parkinson, BG, Holland, D, Smith, ME, Larson, C, Doerr, J, Affatigato, M, Feller, SA, Howes, AP & Scales, CR 2008, 'Quantitative measurement of Q(3) species in silicate and borosilicate glasses using Raman spectroscopy', Journal of Non-Crystalline Solids, vol. 354, no. 17, pp. 1936-1942. https://doi.org/10.1016/j.jnoncrysol.2007.06.105

APA

Parkinson, B. G., Holland, D., Smith, M. E., Larson, C., Doerr, J., Affatigato, M., Feller, S. A., Howes, A. P., & Scales, C. R. (2008). Quantitative measurement of Q(3) species in silicate and borosilicate glasses using Raman spectroscopy. Journal of Non-Crystalline Solids, 354(17), 1936-1942. https://doi.org/10.1016/j.jnoncrysol.2007.06.105

Vancouver

Parkinson BG, Holland D, Smith ME, Larson C, Doerr J, Affatigato M et al. Quantitative measurement of Q(3) species in silicate and borosilicate glasses using Raman spectroscopy. Journal of Non-Crystalline Solids. 2008 Apr 1;354(17):1936-1942. doi: 10.1016/j.jnoncrysol.2007.06.105

Author

Parkinson, B. G. ; Holland, D. ; Smith, Mark E. et al. / Quantitative measurement of Q(3) species in silicate and borosilicate glasses using Raman spectroscopy. In: Journal of Non-Crystalline Solids. 2008 ; Vol. 354, No. 17. pp. 1936-1942.

Bibtex

@article{082af48ffed84f7b9087a2a396a33adf,
title = "Quantitative measurement of Q(3) species in silicate and borosilicate glasses using Raman spectroscopy",
abstract = "Raman spectroscopy has been used to measure the fraction of tetrahedral silicate units connected at three corners into the network (Q(3)) in binary lithium silicate glasses and also in the more complex borosilicate glasses used for waste immobilization. Agreement within experimental error was obtained with Si-29 MAS NMR measurements of the same samples. Raman provides an alternative method of structural determination for silicon-containing glasses with a high content of paramagnetic species where NMR loses resolution. Analysis was performed on borosilicate glasses containing up to 11.98 mol% Fe2O3 and the Q(3) values obtained by Raman spectroscopy agree within error with the published Si-29 NMR results from borosilicate glasses containing the equivalent quantity of Al2O3. (C) 2007 Elsevier B.V. All rights reserved.",
keywords = "glasses, nuclear and chemical wastes, Raman spectroscopy, alkali silicates, borosilicates, silicates, NMR, MAS NMR and NQR, structure",
author = "Parkinson, {B. G.} and D. Holland and Smith, {Mark E.} and C. Larson and J. Doerr and M. Affatigato and Feller, {S. A.} and Howes, {A. P.} and Scales, {C. R.}",
year = "2008",
month = apr,
day = "1",
doi = "10.1016/j.jnoncrysol.2007.06.105",
language = "English",
volume = "354",
pages = "1936--1942",
journal = "Journal of Non-Crystalline Solids",
publisher = "Elsevier",
number = "17",

}

RIS

TY - JOUR

T1 - Quantitative measurement of Q(3) species in silicate and borosilicate glasses using Raman spectroscopy

AU - Parkinson, B. G.

AU - Holland, D.

AU - Smith, Mark E.

AU - Larson, C.

AU - Doerr, J.

AU - Affatigato, M.

AU - Feller, S. A.

AU - Howes, A. P.

AU - Scales, C. R.

PY - 2008/4/1

Y1 - 2008/4/1

N2 - Raman spectroscopy has been used to measure the fraction of tetrahedral silicate units connected at three corners into the network (Q(3)) in binary lithium silicate glasses and also in the more complex borosilicate glasses used for waste immobilization. Agreement within experimental error was obtained with Si-29 MAS NMR measurements of the same samples. Raman provides an alternative method of structural determination for silicon-containing glasses with a high content of paramagnetic species where NMR loses resolution. Analysis was performed on borosilicate glasses containing up to 11.98 mol% Fe2O3 and the Q(3) values obtained by Raman spectroscopy agree within error with the published Si-29 NMR results from borosilicate glasses containing the equivalent quantity of Al2O3. (C) 2007 Elsevier B.V. All rights reserved.

AB - Raman spectroscopy has been used to measure the fraction of tetrahedral silicate units connected at three corners into the network (Q(3)) in binary lithium silicate glasses and also in the more complex borosilicate glasses used for waste immobilization. Agreement within experimental error was obtained with Si-29 MAS NMR measurements of the same samples. Raman provides an alternative method of structural determination for silicon-containing glasses with a high content of paramagnetic species where NMR loses resolution. Analysis was performed on borosilicate glasses containing up to 11.98 mol% Fe2O3 and the Q(3) values obtained by Raman spectroscopy agree within error with the published Si-29 NMR results from borosilicate glasses containing the equivalent quantity of Al2O3. (C) 2007 Elsevier B.V. All rights reserved.

KW - glasses, nuclear and chemical wastes, Raman spectroscopy, alkali silicates, borosilicates, silicates, NMR, MAS NMR and NQR, structure

U2 - 10.1016/j.jnoncrysol.2007.06.105

DO - 10.1016/j.jnoncrysol.2007.06.105

M3 - Journal article

VL - 354

SP - 1936

EP - 1942

JO - Journal of Non-Crystalline Solids

JF - Journal of Non-Crystalline Solids

IS - 17

ER -