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Rationalising the influence of solvent choice on the porosity of conjugated microporous polymers

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Rationalising the influence of solvent choice on the porosity of conjugated microporous polymers. / Mollart, Catherine; Trewin, Abbie.
In: Physical Chemistry Chemical Physics, Vol. 22, No. 38, 20.10.2020, p. 21642-21645.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

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Mollart C, Trewin A. Rationalising the influence of solvent choice on the porosity of conjugated microporous polymers. Physical Chemistry Chemical Physics. 2020 Oct 20;22(38):21642-21645. Epub 2020 Sept 18. doi: 10.1039/D0CP03539D

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Mollart, Catherine ; Trewin, Abbie. / Rationalising the influence of solvent choice on the porosity of conjugated microporous polymers. In: Physical Chemistry Chemical Physics. 2020 ; Vol. 22, No. 38. pp. 21642-21645.

Bibtex

@article{9359b88572fa445c9e7cab8ffcc8b79d,
title = "Rationalising the influence of solvent choice on the porosity of conjugated microporous polymers",
abstract = "Conjugated microporous polymers (CMPs) synthesised in different solvents give different surface areas dependent on the solvent choice. No one solvent results in a high surface area across a range of different CMP materials. Here, we present an investigation into how the porosity of CMPs is affected by solvent polarity. It is seen that the trends differ depending on the respective monomer dipole moments and whether hydrogen bonding groups are present in the monomers and are able to interact with the respective solvent via hydrogen bonding. It is believed that this methodology could be used to influence future materials design of both structure and synthesis strategy.",
author = "Catherine Mollart and Abbie Trewin",
year = "2020",
month = oct,
day = "20",
doi = "10.1039/D0CP03539D",
language = "English",
volume = "22",
pages = "21642--21645",
journal = "Physical Chemistry Chemical Physics",
issn = "1463-9076",
publisher = "Royal Society of Chemistry",
number = "38",

}

RIS

TY - JOUR

T1 - Rationalising the influence of solvent choice on the porosity of conjugated microporous polymers

AU - Mollart, Catherine

AU - Trewin, Abbie

PY - 2020/10/20

Y1 - 2020/10/20

N2 - Conjugated microporous polymers (CMPs) synthesised in different solvents give different surface areas dependent on the solvent choice. No one solvent results in a high surface area across a range of different CMP materials. Here, we present an investigation into how the porosity of CMPs is affected by solvent polarity. It is seen that the trends differ depending on the respective monomer dipole moments and whether hydrogen bonding groups are present in the monomers and are able to interact with the respective solvent via hydrogen bonding. It is believed that this methodology could be used to influence future materials design of both structure and synthesis strategy.

AB - Conjugated microporous polymers (CMPs) synthesised in different solvents give different surface areas dependent on the solvent choice. No one solvent results in a high surface area across a range of different CMP materials. Here, we present an investigation into how the porosity of CMPs is affected by solvent polarity. It is seen that the trends differ depending on the respective monomer dipole moments and whether hydrogen bonding groups are present in the monomers and are able to interact with the respective solvent via hydrogen bonding. It is believed that this methodology could be used to influence future materials design of both structure and synthesis strategy.

U2 - 10.1039/D0CP03539D

DO - 10.1039/D0CP03539D

M3 - Journal article

VL - 22

SP - 21642

EP - 21645

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

SN - 1463-9076

IS - 38

ER -