Rights statement: This is the author’s version of a work that was accepted for publication in International Journal of Hydrogen Energy. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in International Journal of Hydrogen Energy, 43, 41, 2018 DOI: 10.1016/j.ijhydene.2018.08.091
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Final published version
Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
}
TY - JOUR
T1 - Recent advances in cleaner hydrogen productions via thermo-catalytic decomposition of methane: Admixture with hydrocarbon
AU - Syed Muhammad, Anuar Faua'ad
AU - Awad, Ali
AU - Saidur, R.
AU - Masiran, Nurliyana
AU - Salam, Abdus
AU - Abdullah, Bawadi
N1 - This is the author’s version of a work that was accepted for publication in International Journal of Hydrogen Energy. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in International Journal of Hydrogen Energy, 43, 41, 2018 DOI: 10.1016/j.ijhydene.2018.08.091
PY - 2018/10/11
Y1 - 2018/10/11
N2 - A continuous increase in the greenhouse gases concentration due to combustion of fossil fuels for energy generation in the recent decades has sparked interest among the researchers to find a quick solution to this problem. One viable solution is to use hydrogen as a clean and effective source of energy. In this paper, an extensive review has been made on the effectiveness of metallic catalyst in hydrocarbon reforming for COX free hydrogen production via different techniques. Among all metallic catalyst, Ni-based materials impregnated with various transition metals as promoters exhibited prolonged stability, high methane conversions, better thermal resistance and improved coke resistance. This review also assesses the effect of reaction temperature, gas hour space velocity and metal loading on the sustainability of thermocatalytic decomposition TCD of methane. The practice of co-feeding of methane with other hydrocarbons specifically ethylene, propylene, hydrogen sulphide, and ethanol are classified in this paper with the detailed overview of TCD reaction kinetics over an empirical model based on power law that has been presented. In addition, it is also expected that the outlook of TCD of methane for green hydrogen production will provide researchers with an excellent platform to the future direction of the process over Ni-based catalysts.
AB - A continuous increase in the greenhouse gases concentration due to combustion of fossil fuels for energy generation in the recent decades has sparked interest among the researchers to find a quick solution to this problem. One viable solution is to use hydrogen as a clean and effective source of energy. In this paper, an extensive review has been made on the effectiveness of metallic catalyst in hydrocarbon reforming for COX free hydrogen production via different techniques. Among all metallic catalyst, Ni-based materials impregnated with various transition metals as promoters exhibited prolonged stability, high methane conversions, better thermal resistance and improved coke resistance. This review also assesses the effect of reaction temperature, gas hour space velocity and metal loading on the sustainability of thermocatalytic decomposition TCD of methane. The practice of co-feeding of methane with other hydrocarbons specifically ethylene, propylene, hydrogen sulphide, and ethanol are classified in this paper with the detailed overview of TCD reaction kinetics over an empirical model based on power law that has been presented. In addition, it is also expected that the outlook of TCD of methane for green hydrogen production will provide researchers with an excellent platform to the future direction of the process over Ni-based catalysts.
KW - Hydrogen production
KW - Methane conversion
KW - Metallic catalyst
KW - Process parameters
KW - Co-feeding
KW - Reaction kinetics
U2 - 10.1016/j.ijhydene.2018.08.091
DO - 10.1016/j.ijhydene.2018.08.091
M3 - Journal article
VL - 43
SP - 18713
EP - 18734
JO - International Journal of Hydrogen Energy
JF - International Journal of Hydrogen Energy
SN - 0360-3199
IS - 41
ER -