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Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Recent advances in solid-state nuclear magnetic resonance spectroscopy
AU - Ashbrook, Sharon E.
AU - Griffin, John M.
AU - Johnston, Karen E.
N1 - Posted with permission from the Annual Review of Analytical Chemistry, Volume 11© by Annual Reviews, http://www.annualreviews.org.
PY - 2018/6/12
Y1 - 2018/6/12
N2 - The sensitivity of nuclear magnetic resonance (NMR) spectroscopy to the local atomic-scale environment offers great potential for the characterization of a diverse range of solid materials. Despite offering more information than its solution-state counterpart, solid-state NMR has not yet achieved a similar level of recognition, owing to the anisotropic interactions that broaden the spectral lines and hinder the extraction of structural information. Here, we describe the methods available to improve the resolution of solid-state NMR spectra and the continuing research in this area. We also highlight areas of exciting new and future development, including recent interest in combining experiment with theoretical calculations, the rise of a range of polarization transfer techniques that provide significant sensitivity enhancements, and the progress of in situ measurements. We demonstrate the detailed information available when studying dynamic and disordered solids and discuss the future applications of solid-state NMR spectroscopy across the chemical sciences.
AB - The sensitivity of nuclear magnetic resonance (NMR) spectroscopy to the local atomic-scale environment offers great potential for the characterization of a diverse range of solid materials. Despite offering more information than its solution-state counterpart, solid-state NMR has not yet achieved a similar level of recognition, owing to the anisotropic interactions that broaden the spectral lines and hinder the extraction of structural information. Here, we describe the methods available to improve the resolution of solid-state NMR spectra and the continuing research in this area. We also highlight areas of exciting new and future development, including recent interest in combining experiment with theoretical calculations, the rise of a range of polarization transfer techniques that provide significant sensitivity enhancements, and the progress of in situ measurements. We demonstrate the detailed information available when studying dynamic and disordered solids and discuss the future applications of solid-state NMR spectroscopy across the chemical sciences.
KW - solid-state NMR
KW - NMR crystallography
KW - in situ
KW - high-resolution spectroscopy
KW - sensitivity enhancement
KW - MAS NMR-SPECTROSCOPY
KW - HIGH-RESOLUTION NMR
KW - ANGLE-SPINNING NMR
KW - INTEGER QUADRUPOLAR NUCLEI
KW - CONTINUOUS-FLOW CONDITIONS
KW - 1ST-PRINCIPLES CALCULATIONS
KW - NATURAL-ABUNDANCE
KW - MQMAS NMR
KW - CRYSTALLIZATION PROCESSES
KW - HETEROGENEOUS CATALYSIS
U2 - 10.1146/annurev-anchem-061417-125852
DO - 10.1146/annurev-anchem-061417-125852
M3 - Journal article
VL - 11
SP - 485
EP - 508
JO - Annual Review of Analytical Chemistry
JF - Annual Review of Analytical Chemistry
SN - 1936-1335
ER -