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Recent advances in the catalytic generation of N-Acyliminium ions and subsequent applications

Research output: Contribution to Journal/MagazineJournal articlepeer-review

Article number132764
<mark>Journal publication date</mark>21/05/2022
Number of pages27
Publication StatusPublished
<mark>Original language</mark>English


N-acyliminium ions are highly electrophilic reactive intermediates which allow functionalization α to an amide or carbamate. Traditionally accessed using stoichiometric quantities, catalytic generation continually offers greater control and selectivity. This review provides an overview of the most recent advancements in catalytic access to N-acyliminium ions using Brønsted acid, Lewis acid, photoredox and redox mediated pathways.