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Seasonal and diurnal trends in concentrations and fluxes of volatile organic compounds in central London

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Seasonal and diurnal trends in concentrations and fluxes of volatile organic compounds in central London. / Valach, Amy; Langford, Ben; Nemitz, Eiko; MacKenzie, Angus Robert; Hewitt, Charles Nicholas Peter.

In: Atmospheric Chemistry and Physics , Vol. 15, No. 14, 16.07.2015, p. 7777-7796.

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@article{1c485ca602fd4cea99daa7e7977b7819,
title = "Seasonal and diurnal trends in concentrations and fluxes of volatile organic compounds in central London",
abstract = "Concentrations and fluxes of seven volatile organic compounds (VOCs) were measured between August and December 2012 at a rooftop site in central London as part of the ClearfLo project (Clean Air for London). VOC concentrations were quantified using a proton transfer reaction mass spectrometer (PTR-MS) and fluxes were calculated using a virtual disjunct eddy covariance technique. The median VOC fluxes, including aromatics, oxygenated compounds and isoprene, ranged from 0.07 to 0.33 mgm&#x100000;^-2 h^-&#x100000;1. Median mixing ratios were 7.3 ppb for methanol and < 1 ppb for the other compounds. Strong relationships were observed between the fluxes and concentrations of some VOCs with traffic density and between the fluxes and concentrations ofisoprene and oxygenated compounds with photosynthetically active radiation (PAR) and temperature. An estimated 50–90% of the fluxes of aromatic VOCs were attributable to traffic activity, which showed little seasonal variation, suggesting that boundary layer effects or possibly advected pollutionmay be the primary causes of increased concentrations of aromatics in winter. Isoprene, methanol and acetaldehyde fluxes and concentrations in August and September showed high correlations with PAR and temperature, when fluxes andconcentrations were largest suggesting that biogenic sources contributed to their fluxes. Modelled biogenic isoprene fluxes from urban vegetation using the Guenther et al. (1995) algorithm agreed well with measured fluxes in August andSeptember. Comparisons of estimated annual benzene emissions from both the London and the National Atmospheric Emissions Inventories agreed well with measured benzene fluxes. Flux footprint analysis indicated emission sourceswere localised and that boundary layer dynamics and source strengths were responsible for temporal and spatial VOC flux and concentration variability during the measurement period.",
author = "Amy Valach and Ben Langford and Eiko Nemitz and MacKenzie, {Angus Robert} and Hewitt, {Charles Nicholas Peter}",
year = "2015",
month = jul,
day = "16",
doi = "10.5194/acp-15-7777-2015",
language = "English",
volume = "15",
pages = "7777--7796",
journal = "Atmospheric Chemistry and Physics ",
issn = "1680-7316",
publisher = "Copernicus GmbH (Copernicus Publications) on behalf of the European Geosciences Union (EGU)",
number = "14",

}

RIS

TY - JOUR

T1 - Seasonal and diurnal trends in concentrations and fluxes of volatile organic compounds in central London

AU - Valach, Amy

AU - Langford, Ben

AU - Nemitz, Eiko

AU - MacKenzie, Angus Robert

AU - Hewitt, Charles Nicholas Peter

PY - 2015/7/16

Y1 - 2015/7/16

N2 - Concentrations and fluxes of seven volatile organic compounds (VOCs) were measured between August and December 2012 at a rooftop site in central London as part of the ClearfLo project (Clean Air for London). VOC concentrations were quantified using a proton transfer reaction mass spectrometer (PTR-MS) and fluxes were calculated using a virtual disjunct eddy covariance technique. The median VOC fluxes, including aromatics, oxygenated compounds and isoprene, ranged from 0.07 to 0.33 mgm&#x100000;^-2 h^-&#x100000;1. Median mixing ratios were 7.3 ppb for methanol and < 1 ppb for the other compounds. Strong relationships were observed between the fluxes and concentrations of some VOCs with traffic density and between the fluxes and concentrations ofisoprene and oxygenated compounds with photosynthetically active radiation (PAR) and temperature. An estimated 50–90% of the fluxes of aromatic VOCs were attributable to traffic activity, which showed little seasonal variation, suggesting that boundary layer effects or possibly advected pollutionmay be the primary causes of increased concentrations of aromatics in winter. Isoprene, methanol and acetaldehyde fluxes and concentrations in August and September showed high correlations with PAR and temperature, when fluxes andconcentrations were largest suggesting that biogenic sources contributed to their fluxes. Modelled biogenic isoprene fluxes from urban vegetation using the Guenther et al. (1995) algorithm agreed well with measured fluxes in August andSeptember. Comparisons of estimated annual benzene emissions from both the London and the National Atmospheric Emissions Inventories agreed well with measured benzene fluxes. Flux footprint analysis indicated emission sourceswere localised and that boundary layer dynamics and source strengths were responsible for temporal and spatial VOC flux and concentration variability during the measurement period.

AB - Concentrations and fluxes of seven volatile organic compounds (VOCs) were measured between August and December 2012 at a rooftop site in central London as part of the ClearfLo project (Clean Air for London). VOC concentrations were quantified using a proton transfer reaction mass spectrometer (PTR-MS) and fluxes were calculated using a virtual disjunct eddy covariance technique. The median VOC fluxes, including aromatics, oxygenated compounds and isoprene, ranged from 0.07 to 0.33 mgm&#x100000;^-2 h^-&#x100000;1. Median mixing ratios were 7.3 ppb for methanol and < 1 ppb for the other compounds. Strong relationships were observed between the fluxes and concentrations of some VOCs with traffic density and between the fluxes and concentrations ofisoprene and oxygenated compounds with photosynthetically active radiation (PAR) and temperature. An estimated 50–90% of the fluxes of aromatic VOCs were attributable to traffic activity, which showed little seasonal variation, suggesting that boundary layer effects or possibly advected pollutionmay be the primary causes of increased concentrations of aromatics in winter. Isoprene, methanol and acetaldehyde fluxes and concentrations in August and September showed high correlations with PAR and temperature, when fluxes andconcentrations were largest suggesting that biogenic sources contributed to their fluxes. Modelled biogenic isoprene fluxes from urban vegetation using the Guenther et al. (1995) algorithm agreed well with measured fluxes in August andSeptember. Comparisons of estimated annual benzene emissions from both the London and the National Atmospheric Emissions Inventories agreed well with measured benzene fluxes. Flux footprint analysis indicated emission sourceswere localised and that boundary layer dynamics and source strengths were responsible for temporal and spatial VOC flux and concentration variability during the measurement period.

U2 - 10.5194/acp-15-7777-2015

DO - 10.5194/acp-15-7777-2015

M3 - Journal article

VL - 15

SP - 7777

EP - 7796

JO - Atmospheric Chemistry and Physics

JF - Atmospheric Chemistry and Physics

SN - 1680-7316

IS - 14

ER -