Home > Research > Publications & Outputs > Selective electroreduction of glycerol to 1,2-p...

Links

Text available via DOI:

View graph of relations

Selective electroreduction of glycerol to 1,2-propanediol on a mixed carbon-black activated carbon electrode and a mixed carbon black-diamond electrode

Research output: Contribution to Journal/MagazineJournal articlepeer-review

Published

Standard

Selective electroreduction of glycerol to 1,2-propanediol on a mixed carbon-black activated carbon electrode and a mixed carbon black-diamond electrode. / Lee, Ching Shya; Aroua, Mohamed Kheireddine; Daud, Wan Ashri Wan; Cognet, Patrick; Pérès, Yolande; Ajeel, Mohammed A.

In: BioResources, Vol. 13, No. 1, 02.2018, p. 115-130.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

Harvard

APA

Vancouver

Author

Lee, Ching Shya ; Aroua, Mohamed Kheireddine ; Daud, Wan Ashri Wan ; Cognet, Patrick ; Pérès, Yolande ; Ajeel, Mohammed A. / Selective electroreduction of glycerol to 1,2-propanediol on a mixed carbon-black activated carbon electrode and a mixed carbon black-diamond electrode. In: BioResources. 2018 ; Vol. 13, No. 1. pp. 115-130.

Bibtex

@article{132cea7a8a584137be2053b3f945bbaa,
title = "Selective electroreduction of glycerol to 1,2-propanediol on a mixed carbon-black activated carbon electrode and a mixed carbon black-diamond electrode",
abstract = "1,2-propanediol was selectively produced by electroreduction of glycerol in a two-compartment reactor. Two new kinds of cathode electrodes were evaluated: (i) mixed carbon black-activated carbon electrodes and (ii) mixed carbon black-diamond electrodes. These electrodes were compared with a conventional platinum electrode. With a reaction temperature of 80°C, an electric current of 2.0 A, and ambient pressure, the mixed carbon black-activated carbon electrode demonstrated excellent performance and successfully reduced glycerol to 1,2-propanediol with a high selectivity of 86% and 74% glycerol conversion. The selectivity of 1,2-propanediol on the mixed carbon black-diamond electrode and the platinum electrode was 68% and 61%, respectively, with 88% glycerol conversion on the mixed carbon black-diamond electrode and 67% glycerol conversion on the platinum electrode. The authors propose a possible reaction mechanism for the formation of 1,2-PDO.",
keywords = "1,2-Propanediol, Activated carbon, Diamond, Electroreduction, Glycerol",
author = "Lee, {Ching Shya} and Aroua, {Mohamed Kheireddine} and Daud, {Wan Ashri Wan} and Patrick Cognet and Yolande P{\'e}r{\`e}s and Ajeel, {Mohammed A.}",
year = "2018",
month = feb,
doi = "10.15376/biores.13.1.115-130",
language = "English",
volume = "13",
pages = "115--130",
journal = "BioResources",
issn = "1930-2126",
publisher = "North Carolina University",
number = "1",

}

RIS

TY - JOUR

T1 - Selective electroreduction of glycerol to 1,2-propanediol on a mixed carbon-black activated carbon electrode and a mixed carbon black-diamond electrode

AU - Lee, Ching Shya

AU - Aroua, Mohamed Kheireddine

AU - Daud, Wan Ashri Wan

AU - Cognet, Patrick

AU - Pérès, Yolande

AU - Ajeel, Mohammed A.

PY - 2018/2

Y1 - 2018/2

N2 - 1,2-propanediol was selectively produced by electroreduction of glycerol in a two-compartment reactor. Two new kinds of cathode electrodes were evaluated: (i) mixed carbon black-activated carbon electrodes and (ii) mixed carbon black-diamond electrodes. These electrodes were compared with a conventional platinum electrode. With a reaction temperature of 80°C, an electric current of 2.0 A, and ambient pressure, the mixed carbon black-activated carbon electrode demonstrated excellent performance and successfully reduced glycerol to 1,2-propanediol with a high selectivity of 86% and 74% glycerol conversion. The selectivity of 1,2-propanediol on the mixed carbon black-diamond electrode and the platinum electrode was 68% and 61%, respectively, with 88% glycerol conversion on the mixed carbon black-diamond electrode and 67% glycerol conversion on the platinum electrode. The authors propose a possible reaction mechanism for the formation of 1,2-PDO.

AB - 1,2-propanediol was selectively produced by electroreduction of glycerol in a two-compartment reactor. Two new kinds of cathode electrodes were evaluated: (i) mixed carbon black-activated carbon electrodes and (ii) mixed carbon black-diamond electrodes. These electrodes were compared with a conventional platinum electrode. With a reaction temperature of 80°C, an electric current of 2.0 A, and ambient pressure, the mixed carbon black-activated carbon electrode demonstrated excellent performance and successfully reduced glycerol to 1,2-propanediol with a high selectivity of 86% and 74% glycerol conversion. The selectivity of 1,2-propanediol on the mixed carbon black-diamond electrode and the platinum electrode was 68% and 61%, respectively, with 88% glycerol conversion on the mixed carbon black-diamond electrode and 67% glycerol conversion on the platinum electrode. The authors propose a possible reaction mechanism for the formation of 1,2-PDO.

KW - 1,2-Propanediol

KW - Activated carbon

KW - Diamond

KW - Electroreduction

KW - Glycerol

U2 - 10.15376/biores.13.1.115-130

DO - 10.15376/biores.13.1.115-130

M3 - Journal article

AN - SCOPUS:85041301493

VL - 13

SP - 115

EP - 130

JO - BioResources

JF - BioResources

SN - 1930-2126

IS - 1

ER -