Final published version
Research output: Contribution in Book/Report/Proceedings - With ISBN/ISSN › Chapter
Research output: Contribution in Book/Report/Proceedings - With ISBN/ISSN › Chapter
}
TY - CHAP
T1 - Solid-state NMR of energy storage materials
AU - Griffith, Kent J.
AU - Griffin, John M.
N1 - Publisher Copyright: © 2023 Elsevier Ltd. All rights reserved
PY - 2023/1/1
Y1 - 2023/1/1
N2 - Electrochemical energy storage in batteries and supercapacitors underlies portable technology and is enabling the shift away from fossil fuels and toward electric vehicles and increased adoption of intermittent renewable power sources. Understanding reaction and degradation mechanisms is the key to unlocking the next generation of energy storage materials. This chapter will highlight the diverse applicability and chemical sensitivity of solid-state NMR as a tool for studying bulk and interfacial structures and dynamics. NMR interactions relevant to inorganic battery and supercapacitor materials will be described before moving into sections on lithium battery cathodes, anodes, solid electrolytes, interfaces, and finally supercapacitors. While battery materials vary in maturity, each section focuses on materials that are either in commercial use or development. Multinuclear NMR studies of mechanisms, atomic structure, and ion dynamics are succinctly described and an effort is made to summarize the state of the field for each class of materials.
AB - Electrochemical energy storage in batteries and supercapacitors underlies portable technology and is enabling the shift away from fossil fuels and toward electric vehicles and increased adoption of intermittent renewable power sources. Understanding reaction and degradation mechanisms is the key to unlocking the next generation of energy storage materials. This chapter will highlight the diverse applicability and chemical sensitivity of solid-state NMR as a tool for studying bulk and interfacial structures and dynamics. NMR interactions relevant to inorganic battery and supercapacitor materials will be described before moving into sections on lithium battery cathodes, anodes, solid electrolytes, interfaces, and finally supercapacitors. While battery materials vary in maturity, each section focuses on materials that are either in commercial use or development. Multinuclear NMR studies of mechanisms, atomic structure, and ion dynamics are succinctly described and an effort is made to summarize the state of the field for each class of materials.
KW - Batteries
KW - Diffusion
KW - Dynamics
KW - Electrochemistry
KW - Energy storage
KW - Ion conductors
KW - ithium metal
KW - Lithium-ion
KW - Mixed ionic-electronic conductors (MIEC)
KW - Nuclear magnetic resonance (NMR) spectroscopy
KW - Solid-state NMR
KW - Supercapacitors
KW - Surface-electrolyte interphase (SEI)
UR - http://www.scopus.com/inward/record.url?scp=85152642779&partnerID=8YFLogxK
U2 - 10.1016/B978-0-12-823144-9.00147-3
DO - 10.1016/B978-0-12-823144-9.00147-3
M3 - Chapter
AN - SCOPUS:85152642779
VL - 1-10
SP - 282
EP - 329
BT - Comprehensive Inorganic Chemistry III, Third Edition
A2 - Reedijk, Jan
A2 - Poeppelmeier, Kenneth R.
PB - Elsevier
ER -