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Solid-state NMR of high-pressure silicates in the Earth's mantle

Research output: Contribution in Book/Report/Proceedings - With ISBN/ISSNChapter

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Standard

Solid-state NMR of high-pressure silicates in the Earth's mantle. / Griffin, John M.; Ashbrook, Sharon E.

Annual Reports on NMR Spectroscopy. ed. / GA Webb. San Diego : Elsevier Academic Press, 2013. p. 241-332 (Annual Reports on NMR Spectroscopy; Vol. 79).

Research output: Contribution in Book/Report/Proceedings - With ISBN/ISSNChapter

Harvard

Griffin, JM & Ashbrook, SE 2013, Solid-state NMR of high-pressure silicates in the Earth's mantle. in GA Webb (ed.), Annual Reports on NMR Spectroscopy. Annual Reports on NMR Spectroscopy, vol. 79, Elsevier Academic Press, San Diego, pp. 241-332. https://doi.org/10.1016/B978-0-12-408098-0.00005-7

APA

Griffin, J. M., & Ashbrook, S. E. (2013). Solid-state NMR of high-pressure silicates in the Earth's mantle. In GA. Webb (Ed.), Annual Reports on NMR Spectroscopy (pp. 241-332). (Annual Reports on NMR Spectroscopy; Vol. 79). Elsevier Academic Press. https://doi.org/10.1016/B978-0-12-408098-0.00005-7

Vancouver

Griffin JM, Ashbrook SE. Solid-state NMR of high-pressure silicates in the Earth's mantle. In Webb GA, editor, Annual Reports on NMR Spectroscopy. San Diego: Elsevier Academic Press. 2013. p. 241-332. (Annual Reports on NMR Spectroscopy). https://doi.org/10.1016/B978-0-12-408098-0.00005-7

Author

Griffin, John M. ; Ashbrook, Sharon E. / Solid-state NMR of high-pressure silicates in the Earth's mantle. Annual Reports on NMR Spectroscopy. editor / GA Webb. San Diego : Elsevier Academic Press, 2013. pp. 241-332 (Annual Reports on NMR Spectroscopy).

Bibtex

@inbook{ad727fa139164846983762466a48db8b,
title = "Solid-state NMR of high-pressure silicates in the Earth's mantle",
abstract = "The Earth's mantle is primarily composed of solid silicates, which undergo a number of phase transitions with increasing pressure and temperature. A detailed knowledge of these phases is integral to our understanding of the physical and chemical properties of the inner Earth. In particular, the Earth's mantle is believed to contain a large amount of water that is at least equivalent to that present in the oceans and atmosphere; however, the way in which this water is stored within the mantle is not well understood. Nuclear magnetic resonance (NMR) spectroscopy can offer an unparalleled insight into the structure, disorder and dynamics on the atomic scale, making it an ideal probe for such systems. In this review, we explore applications of NMR spectroscopy for the study of high-pressure silicates in the Earth's mantle. We first highlight some of the experimental techniques used and discuss the properties of NMR-active nuclei that are relevant to the study of high-pressure silicates. After summarising the chemical nature of the Earth's mantle and discussing synthetic methods for the preparation of the silicate phases present at different depths, we then review applications of NMR spectroscopy for the study of mantle silicates with a particular focus on the hydration of nominally anhydrous minerals.",
keywords = "NMR, Silicates, High pressure, Hydrous minerals, Oxygen-17, DFT calculations, HYDROUS MAGNESIUM SILICATES, NUCLEAR-MAGNETIC-RESONANCE, NOMINALLY ANHYDROUS MINERALS, QUANTUM MAS NMR, CRYSTAL X-RAY, INTEGER QUADRUPOLAR NUCLEI, ELECTRIC-FIELD-GRADIENT, RESOLUTION O-17 NMR, ANGLE-SPINNING NMR, POWDER NEUTRON-DIFFRACTION",
author = "Griffin, {John M.} and Ashbrook, {Sharon E.}",
year = "2013",
doi = "10.1016/B978-0-12-408098-0.00005-7",
language = "English",
isbn = "9780124080980",
series = "Annual Reports on NMR Spectroscopy",
publisher = "Elsevier Academic Press",
pages = "241--332",
editor = "GA Webb",
booktitle = "Annual Reports on NMR Spectroscopy",

}

RIS

TY - CHAP

T1 - Solid-state NMR of high-pressure silicates in the Earth's mantle

AU - Griffin, John M.

AU - Ashbrook, Sharon E.

PY - 2013

Y1 - 2013

N2 - The Earth's mantle is primarily composed of solid silicates, which undergo a number of phase transitions with increasing pressure and temperature. A detailed knowledge of these phases is integral to our understanding of the physical and chemical properties of the inner Earth. In particular, the Earth's mantle is believed to contain a large amount of water that is at least equivalent to that present in the oceans and atmosphere; however, the way in which this water is stored within the mantle is not well understood. Nuclear magnetic resonance (NMR) spectroscopy can offer an unparalleled insight into the structure, disorder and dynamics on the atomic scale, making it an ideal probe for such systems. In this review, we explore applications of NMR spectroscopy for the study of high-pressure silicates in the Earth's mantle. We first highlight some of the experimental techniques used and discuss the properties of NMR-active nuclei that are relevant to the study of high-pressure silicates. After summarising the chemical nature of the Earth's mantle and discussing synthetic methods for the preparation of the silicate phases present at different depths, we then review applications of NMR spectroscopy for the study of mantle silicates with a particular focus on the hydration of nominally anhydrous minerals.

AB - The Earth's mantle is primarily composed of solid silicates, which undergo a number of phase transitions with increasing pressure and temperature. A detailed knowledge of these phases is integral to our understanding of the physical and chemical properties of the inner Earth. In particular, the Earth's mantle is believed to contain a large amount of water that is at least equivalent to that present in the oceans and atmosphere; however, the way in which this water is stored within the mantle is not well understood. Nuclear magnetic resonance (NMR) spectroscopy can offer an unparalleled insight into the structure, disorder and dynamics on the atomic scale, making it an ideal probe for such systems. In this review, we explore applications of NMR spectroscopy for the study of high-pressure silicates in the Earth's mantle. We first highlight some of the experimental techniques used and discuss the properties of NMR-active nuclei that are relevant to the study of high-pressure silicates. After summarising the chemical nature of the Earth's mantle and discussing synthetic methods for the preparation of the silicate phases present at different depths, we then review applications of NMR spectroscopy for the study of mantle silicates with a particular focus on the hydration of nominally anhydrous minerals.

KW - NMR

KW - Silicates

KW - High pressure

KW - Hydrous minerals

KW - Oxygen-17

KW - DFT calculations

KW - HYDROUS MAGNESIUM SILICATES

KW - NUCLEAR-MAGNETIC-RESONANCE

KW - NOMINALLY ANHYDROUS MINERALS

KW - QUANTUM MAS NMR

KW - CRYSTAL X-RAY

KW - INTEGER QUADRUPOLAR NUCLEI

KW - ELECTRIC-FIELD-GRADIENT

KW - RESOLUTION O-17 NMR

KW - ANGLE-SPINNING NMR

KW - POWDER NEUTRON-DIFFRACTION

U2 - 10.1016/B978-0-12-408098-0.00005-7

DO - 10.1016/B978-0-12-408098-0.00005-7

M3 - Chapter

SN - 9780124080980

T3 - Annual Reports on NMR Spectroscopy

SP - 241

EP - 332

BT - Annual Reports on NMR Spectroscopy

A2 - Webb, GA

PB - Elsevier Academic Press

CY - San Diego

ER -