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Solubility of mixtures containing soybean oil, ionic liquid and methanol

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Solubility of mixtures containing soybean oil, ionic liquid and methanol. / Manic, Marina S.; Najdanovic, Vesna.

In: The Open Chemical Engineering Journal, Vol. 10, No. Suppl. 1, 08.04.2016, p. 41-49.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

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Manic, MS & Najdanovic, V 2016, 'Solubility of mixtures containing soybean oil, ionic liquid and methanol', The Open Chemical Engineering Journal, vol. 10, no. Suppl. 1, pp. 41-49. https://doi.org/10.2174/1874123101610010041

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Manic, Marina S. ; Najdanovic, Vesna. / Solubility of mixtures containing soybean oil, ionic liquid and methanol. In: The Open Chemical Engineering Journal. 2016 ; Vol. 10, No. Suppl. 1. pp. 41-49.

Bibtex

@article{dad0091e961844a9b203b8f4b477c907,
title = "Solubility of mixtures containing soybean oil, ionic liquid and methanol",
abstract = "This paper presents data on mutual solubility of the binary (soybean oil + ionic liquid) and ternary (soybean oil + methanol + ionic liquid) systems, where ionic liquid stands for 1-butyl-3-methylimidazolium thiocyanate [C4MIM][SCN] or 1-butyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl)imide [C4MIM][NTf2] or 1-butyl-3-methylimidazolium dicyanamide [C4MIM][DCA] or 1-butyl-3-methylimidazolium hexafluorophosphate [C4MIM][PF6] or 1-butyl-3-methyl imida zolium hydrogensulfate [C4MIM] [HSO4] or 1-decyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide [C10MIM][NTf2] or methyltrioctylammonium bis(trifluoromethylsulfonyl)imide [ALIQUAT][NTf2] or methyltrioctylammonium chloride [ALIQUAT][Cl]. Solubilities were determined by the cloud point titration method in the temperature range of 298 K to 343 K. Obtained results suggest that imidazolium based ionic liquids exhibit lower solubility in soybean oil than ionic liquids with the aliquat cation. Thus, aliquat based ionic liquids are good candidate to be used as co-solvents for biphasic (methanol + soybean oil) mixture.",
keywords = "Biodiesel, Ionic liquids, Solubility soybean oil, Methanol",
author = "Manic, {Marina S.} and Vesna Najdanovic",
note = "Open-Access License: This is an open access article licensed under the terms of the Creative Commons Attribution-Non-Commercial 4.0 International Public License (CC BY-NC 4.0) (https://creativecommons.org/licenses/by-nc/4.0/legalcode), which permits unrestricted, non-commercial use, distribution and reproduction in any medium, provided the work is properly cited.",
year = "2016",
month = apr,
day = "8",
doi = "10.2174/1874123101610010041",
language = "English",
volume = "10",
pages = "41--49",
journal = "The Open Chemical Engineering Journal",
issn = "1874-1231",
publisher = "Bentham Science Publishers B.V.",
number = "Suppl. 1",

}

RIS

TY - JOUR

T1 - Solubility of mixtures containing soybean oil, ionic liquid and methanol

AU - Manic, Marina S.

AU - Najdanovic, Vesna

N1 - Open-Access License: This is an open access article licensed under the terms of the Creative Commons Attribution-Non-Commercial 4.0 International Public License (CC BY-NC 4.0) (https://creativecommons.org/licenses/by-nc/4.0/legalcode), which permits unrestricted, non-commercial use, distribution and reproduction in any medium, provided the work is properly cited.

PY - 2016/4/8

Y1 - 2016/4/8

N2 - This paper presents data on mutual solubility of the binary (soybean oil + ionic liquid) and ternary (soybean oil + methanol + ionic liquid) systems, where ionic liquid stands for 1-butyl-3-methylimidazolium thiocyanate [C4MIM][SCN] or 1-butyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl)imide [C4MIM][NTf2] or 1-butyl-3-methylimidazolium dicyanamide [C4MIM][DCA] or 1-butyl-3-methylimidazolium hexafluorophosphate [C4MIM][PF6] or 1-butyl-3-methyl imida zolium hydrogensulfate [C4MIM] [HSO4] or 1-decyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide [C10MIM][NTf2] or methyltrioctylammonium bis(trifluoromethylsulfonyl)imide [ALIQUAT][NTf2] or methyltrioctylammonium chloride [ALIQUAT][Cl]. Solubilities were determined by the cloud point titration method in the temperature range of 298 K to 343 K. Obtained results suggest that imidazolium based ionic liquids exhibit lower solubility in soybean oil than ionic liquids with the aliquat cation. Thus, aliquat based ionic liquids are good candidate to be used as co-solvents for biphasic (methanol + soybean oil) mixture.

AB - This paper presents data on mutual solubility of the binary (soybean oil + ionic liquid) and ternary (soybean oil + methanol + ionic liquid) systems, where ionic liquid stands for 1-butyl-3-methylimidazolium thiocyanate [C4MIM][SCN] or 1-butyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl)imide [C4MIM][NTf2] or 1-butyl-3-methylimidazolium dicyanamide [C4MIM][DCA] or 1-butyl-3-methylimidazolium hexafluorophosphate [C4MIM][PF6] or 1-butyl-3-methyl imida zolium hydrogensulfate [C4MIM] [HSO4] or 1-decyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide [C10MIM][NTf2] or methyltrioctylammonium bis(trifluoromethylsulfonyl)imide [ALIQUAT][NTf2] or methyltrioctylammonium chloride [ALIQUAT][Cl]. Solubilities were determined by the cloud point titration method in the temperature range of 298 K to 343 K. Obtained results suggest that imidazolium based ionic liquids exhibit lower solubility in soybean oil than ionic liquids with the aliquat cation. Thus, aliquat based ionic liquids are good candidate to be used as co-solvents for biphasic (methanol + soybean oil) mixture.

KW - Biodiesel

KW - Ionic liquids

KW - Solubility soybean oil

KW - Methanol

U2 - 10.2174/1874123101610010041

DO - 10.2174/1874123101610010041

M3 - Journal article

VL - 10

SP - 41

EP - 49

JO - The Open Chemical Engineering Journal

JF - The Open Chemical Engineering Journal

SN - 1874-1231

IS - Suppl. 1

ER -