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Stereochemical studies of cobalt ethylenediamine complexes and their tetrathionate salts: interactions between complex configuration and tetrathionate conformation

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Stereochemical studies of cobalt ethylenediamine complexes and their tetrathionate salts: interactions between complex configuration and tetrathionate conformation. / Casadesus, Meritxell ; Coogan, Michael; Davies, Elenna et al.
In: Inorganica Chimica Acta, Vol. 361, No. 1, 2008, p. 63-78.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Casadesus, M, Coogan, M, Davies, E & Ooi, L 2008, 'Stereochemical studies of cobalt ethylenediamine complexes and their tetrathionate salts: interactions between complex configuration and tetrathionate conformation', Inorganica Chimica Acta, vol. 361, no. 1, pp. 63-78. https://doi.org/10.1016/j.ica.2007.06.033

APA

Casadesus, M., Coogan, M., Davies, E., & Ooi, L. (2008). Stereochemical studies of cobalt ethylenediamine complexes and their tetrathionate salts: interactions between complex configuration and tetrathionate conformation. Inorganica Chimica Acta, 361(1), 63-78. https://doi.org/10.1016/j.ica.2007.06.033

Vancouver

Casadesus M, Coogan M, Davies E, Ooi L. Stereochemical studies of cobalt ethylenediamine complexes and their tetrathionate salts: interactions between complex configuration and tetrathionate conformation. Inorganica Chimica Acta. 2008;361(1):63-78. doi: 10.1016/j.ica.2007.06.033

Author

Casadesus, Meritxell ; Coogan, Michael ; Davies, Elenna et al. / Stereochemical studies of cobalt ethylenediamine complexes and their tetrathionate salts : interactions between complex configuration and tetrathionate conformation. In: Inorganica Chimica Acta. 2008 ; Vol. 361, No. 1. pp. 63-78.

Bibtex

@article{9a35b933d7fd46c29206c0675c6d43a5,
title = "Stereochemical studies of cobalt ethylenediamine complexes and their tetrathionate salts: interactions between complex configuration and tetrathionate conformation",
abstract = "A range of chiral coordination complexes of the formulae cis-[Co(en)2XY] where X, Y = hal, NH3, NO2, ox, SCN have been prepared as the halide or pseudohalide salts, and the novel examples have been structurally characterised and their stereochemical behaviour studied. Salt metathesis of certain of these species to the corresponding tetrathionates is described, and the tetrathionates structurally characterised and the stereochemical relationship between the conformations of the chiral complexes and the pseudochiral tetrathionates analysed. The patterns of cation–cation and cation–anion interactions are discussed in the context of the reported ability of the tetrathionate ion to induce conglomerate crystallisation in such species, and tetrathionate chirality in the literature.",
author = "Meritxell Casadesus and Michael Coogan and Elenna Davies and Li-ling Ooi",
year = "2008",
doi = "10.1016/j.ica.2007.06.033",
language = "English",
volume = "361",
pages = "63--78",
journal = "Inorganica Chimica Acta",
publisher = "Elsevier S.A.",
number = "1",

}

RIS

TY - JOUR

T1 - Stereochemical studies of cobalt ethylenediamine complexes and their tetrathionate salts

T2 - interactions between complex configuration and tetrathionate conformation

AU - Casadesus, Meritxell

AU - Coogan, Michael

AU - Davies, Elenna

AU - Ooi, Li-ling

PY - 2008

Y1 - 2008

N2 - A range of chiral coordination complexes of the formulae cis-[Co(en)2XY] where X, Y = hal, NH3, NO2, ox, SCN have been prepared as the halide or pseudohalide salts, and the novel examples have been structurally characterised and their stereochemical behaviour studied. Salt metathesis of certain of these species to the corresponding tetrathionates is described, and the tetrathionates structurally characterised and the stereochemical relationship between the conformations of the chiral complexes and the pseudochiral tetrathionates analysed. The patterns of cation–cation and cation–anion interactions are discussed in the context of the reported ability of the tetrathionate ion to induce conglomerate crystallisation in such species, and tetrathionate chirality in the literature.

AB - A range of chiral coordination complexes of the formulae cis-[Co(en)2XY] where X, Y = hal, NH3, NO2, ox, SCN have been prepared as the halide or pseudohalide salts, and the novel examples have been structurally characterised and their stereochemical behaviour studied. Salt metathesis of certain of these species to the corresponding tetrathionates is described, and the tetrathionates structurally characterised and the stereochemical relationship between the conformations of the chiral complexes and the pseudochiral tetrathionates analysed. The patterns of cation–cation and cation–anion interactions are discussed in the context of the reported ability of the tetrathionate ion to induce conglomerate crystallisation in such species, and tetrathionate chirality in the literature.

U2 - 10.1016/j.ica.2007.06.033

DO - 10.1016/j.ica.2007.06.033

M3 - Journal article

VL - 361

SP - 63

EP - 78

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -