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Strategies for the Controlled Hydrostannylation of Alkynes

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Article numbere202300755
<mark>Journal publication date</mark>7/11/2023
<mark>Journal</mark>European Journal of Organic Chemistry
Issue number42
Number of pages6
Publication StatusPublished
Early online date27/09/23
<mark>Original language</mark>English


Organostannanes have represented one of the most widely applied reagents in modern cross‐coupling chemistry and represent a key reagent in the synthesis of a range of pharmaceutically relevant scaffolds. This Concept article summarizes recent advances in approaches to the synthesis of these building blocks in a stereocontrolled and regiocontrolled manner. Particular focus is paid to methods which allow for divergent synthesis of alkenylstannanes and developments in methods which present opportunities for sustainable synthesis..