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Structural influences on high-resolution yttrium-89 NMR spectra of solids

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Structural influences on high-resolution yttrium-89 NMR spectra of solids. / Dupree, R.; Smith, M.E.

In: Chemical Physics Letters, Vol. 148, No. 1, 07.1988, p. 41-44.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Dupree, R & Smith, ME 1988, 'Structural influences on high-resolution yttrium-89 NMR spectra of solids', Chemical Physics Letters, vol. 148, no. 1, pp. 41-44. https://doi.org/10.1016/0009-2614(88)87257-9

APA

Dupree, R., & Smith, M. E. (1988). Structural influences on high-resolution yttrium-89 NMR spectra of solids. Chemical Physics Letters, 148(1), 41-44. https://doi.org/10.1016/0009-2614(88)87257-9

Vancouver

Dupree R, Smith ME. Structural influences on high-resolution yttrium-89 NMR spectra of solids. Chemical Physics Letters. 1988 Jul;148(1):41-44. doi: 10.1016/0009-2614(88)87257-9

Author

Dupree, R. ; Smith, M.E. / Structural influences on high-resolution yttrium-89 NMR spectra of solids. In: Chemical Physics Letters. 1988 ; Vol. 148, No. 1. pp. 41-44.

Bibtex

@article{a3ce782181b24e92bf4c385c7da57415,
title = "Structural influences on high-resolution yttrium-89 NMR spectra of solids",
abstract = "Structural influences on both the isotropic NMR chemical shift and resonance linewidth of 89Y are investigated by obtaining magic-angle spinning NMR spectra from a number of solid-state yttrium aluminate and silicate phases. These clearly show that the isotropic chemical shift for 89Y is dependent on the number of nearest neighbours and the nature of the next-nearest neighbours. However, unlike most other nuclei such as 29Si and 27Al, the shift ranges of different nearest-neighbour coordinations significantly overlap. In the silicates the 89Y spectrum becomes more shielded as the 29Si resonance becomes less shielded reflecting the reciprocity of the shifts. {\textcopyright} 1988.",
author = "R. Dupree and M.E. Smith",
year = "1988",
month = jul,
doi = "10.1016/0009-2614(88)87257-9",
language = "English",
volume = "148",
pages = "41--44",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "1",

}

RIS

TY - JOUR

T1 - Structural influences on high-resolution yttrium-89 NMR spectra of solids

AU - Dupree, R.

AU - Smith, M.E.

PY - 1988/7

Y1 - 1988/7

N2 - Structural influences on both the isotropic NMR chemical shift and resonance linewidth of 89Y are investigated by obtaining magic-angle spinning NMR spectra from a number of solid-state yttrium aluminate and silicate phases. These clearly show that the isotropic chemical shift for 89Y is dependent on the number of nearest neighbours and the nature of the next-nearest neighbours. However, unlike most other nuclei such as 29Si and 27Al, the shift ranges of different nearest-neighbour coordinations significantly overlap. In the silicates the 89Y spectrum becomes more shielded as the 29Si resonance becomes less shielded reflecting the reciprocity of the shifts. © 1988.

AB - Structural influences on both the isotropic NMR chemical shift and resonance linewidth of 89Y are investigated by obtaining magic-angle spinning NMR spectra from a number of solid-state yttrium aluminate and silicate phases. These clearly show that the isotropic chemical shift for 89Y is dependent on the number of nearest neighbours and the nature of the next-nearest neighbours. However, unlike most other nuclei such as 29Si and 27Al, the shift ranges of different nearest-neighbour coordinations significantly overlap. In the silicates the 89Y spectrum becomes more shielded as the 29Si resonance becomes less shielded reflecting the reciprocity of the shifts. © 1988.

U2 - 10.1016/0009-2614(88)87257-9

DO - 10.1016/0009-2614(88)87257-9

M3 - Journal article

VL - 148

SP - 41

EP - 44

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 1

ER -