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Structural investigations of transition metal (II) tetracyanonickelate complexes of 3-chloropyridine using Fourier transform-infrared and laser Raman spectroscopy.

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Structural investigations of transition metal (II) tetracyanonickelate complexes of 3-chloropyridine using Fourier transform-infrared and laser Raman spectroscopy. / Akyüz, S.; Akyüz, T.; Davies, D. et al.
In: Journal of Molecular Structure, Vol. 265, No. 1-2, 1992, p. 85-92.

Research output: Contribution to Journal/Magazine › Journal article

Harvard

Akyüz, S, Akyüz, T, Davies, D & Eric, J 1992, 'Structural investigations of transition metal (II) tetracyanonickelate complexes of 3-chloropyridine using Fourier transform-infrared and laser Raman spectroscopy.', Journal of Molecular Structure, vol. 265, no. 1-2, pp. 85-92. https://doi.org/10.1016/0022-2860(92)80240-I

APA

Akyüz, S., Akyüz, T., Davies, D., & Eric, J. (1992). Structural investigations of transition metal (II) tetracyanonickelate complexes of 3-chloropyridine using Fourier transform-infrared and laser Raman spectroscopy. Journal of Molecular Structure, 265(1-2), 85-92. https://doi.org/10.1016/0022-2860(92)80240-I

Vancouver

Akyüz S, Akyüz T, Davies D, Eric J. Structural investigations of transition metal (II) tetracyanonickelate complexes of 3-chloropyridine using Fourier transform-infrared and laser Raman spectroscopy. Journal of Molecular Structure. 1992;265(1-2):85-92. doi: 10.1016/0022-2860(92)80240-I

Author

Akyüz, S. ; Akyüz, T. ; Davies, D. et al. / Structural investigations of transition metal (II) tetracyanonickelate complexes of 3-chloropyridine using Fourier transform-infrared and laser Raman spectroscopy. In: Journal of Molecular Structure. 1992 ; Vol. 265, No. 1-2. pp. 85-92.

Bibtex

@article{de79a1b45e69443c86500ec8c80d2600,
title = "Structural investigations of transition metal (II) tetracyanonickelate complexes of 3-chloropyridine using Fourier transform-infrared and laser Raman spectroscopy.",
abstract = "The FT-IR and laser-Raman spectra of five new complexes of the formula ML2Ni(CN)4 (where M=Mn, Fe, Ni, Zn or Cd; L=3-chloropyridine) are reported. The complexes are shown to have a structure consisting of two dimensional polymeric layers formed with Ni(CN)4 ions bridged by ML2 cations. For a given series of isomorphous complexes, the effects of metal ligand bond formation on the ligand vibrational modes are examined and the metal-sensitivity sequence of the ligand frequencies is found to be Mn≈Cd<Fe<Zn<Ni.",
author = "S. Aky{\"u}z and T. Aky{\"u}z and D. Davies and J. Eric",
year = "1992",
doi = "10.1016/0022-2860(92)80240-I",
language = "English",
volume = "265",
pages = "85--92",
journal = "Journal of Molecular Structure",
publisher = "Elsevier",
number = "1-2",

}

RIS

TY - JOUR

T1 - Structural investigations of transition metal (II) tetracyanonickelate complexes of 3-chloropyridine using Fourier transform-infrared and laser Raman spectroscopy.

AU - Akyüz, S.

AU - Akyüz, T.

AU - Davies, D.

AU - Eric, J.

PY - 1992

Y1 - 1992

N2 - The FT-IR and laser-Raman spectra of five new complexes of the formula ML2Ni(CN)4 (where M=Mn, Fe, Ni, Zn or Cd; L=3-chloropyridine) are reported. The complexes are shown to have a structure consisting of two dimensional polymeric layers formed with Ni(CN)4 ions bridged by ML2 cations. For a given series of isomorphous complexes, the effects of metal ligand bond formation on the ligand vibrational modes are examined and the metal-sensitivity sequence of the ligand frequencies is found to be Mn≈Cd<Fe<Zn<Ni.

AB - The FT-IR and laser-Raman spectra of five new complexes of the formula ML2Ni(CN)4 (where M=Mn, Fe, Ni, Zn or Cd; L=3-chloropyridine) are reported. The complexes are shown to have a structure consisting of two dimensional polymeric layers formed with Ni(CN)4 ions bridged by ML2 cations. For a given series of isomorphous complexes, the effects of metal ligand bond formation on the ligand vibrational modes are examined and the metal-sensitivity sequence of the ligand frequencies is found to be Mn≈Cd<Fe<Zn<Ni.

U2 - 10.1016/0022-2860(92)80240-I

DO - 10.1016/0022-2860(92)80240-I

M3 - Journal article

VL - 265

SP - 85

EP - 92

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1-2

ER -