Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Syntheses and structures of iron(III) complexes of simple N-donor ligands
AU - Cotton, Simon A.
AU - Franckevicius, Vilius
AU - Fawcett, John
PY - 2002/9/1
Y1 - 2002/9/1
N2 - Syntheses and structures of mer-[FeCl3(pyrazole)(3)] (1), mer-[FeCl3(N-methylimidazole)(3)] (2), mer-[FeCl3(terpy)] (3) (terpy = 2,2': 6',2"-terpyridine), mer-[FeCl3(tptz)] (4) (tptz=2,4,6-tris(2-pyridyl)-1,3,5-triazine) and trans -[FeCl2(3-methylpyrazole)(4)]Cl (5) are reported. The structures demonstrate intramolecular N-H...Cl; imramolecular C-H... Cl; and intermolecular N-H...Cl interactions. Syntheses and analytical data are also reported for [FeCl3(imidazole)(4)] (6), but crystals suitable for X-ray study were not obtained. (C) 2002 Elsevier Science Ltd. All rights reserved.
AB - Syntheses and structures of mer-[FeCl3(pyrazole)(3)] (1), mer-[FeCl3(N-methylimidazole)(3)] (2), mer-[FeCl3(terpy)] (3) (terpy = 2,2': 6',2"-terpyridine), mer-[FeCl3(tptz)] (4) (tptz=2,4,6-tris(2-pyridyl)-1,3,5-triazine) and trans -[FeCl2(3-methylpyrazole)(4)]Cl (5) are reported. The structures demonstrate intramolecular N-H...Cl; imramolecular C-H... Cl; and intermolecular N-H...Cl interactions. Syntheses and analytical data are also reported for [FeCl3(imidazole)(4)] (6), but crystals suitable for X-ray study were not obtained. (C) 2002 Elsevier Science Ltd. All rights reserved.
KW - single-crystal X-ray
KW - SPECTRA
KW - MOLECULAR-STRUCTURE
KW - CRYSTAL
KW - DERIVATIVES
KW - CHLORIDE ALPHA,ALPHA'-DIIMINE SYSTEM
KW - N-donor
KW - CR
KW - terpyridyl
KW - iron(III)
U2 - 10.1016/S0277-5387(02)01137-3
DO - 10.1016/S0277-5387(02)01137-3
M3 - Journal article
VL - 21
SP - 2055
EP - 2061
JO - Polyhedron
JF - Polyhedron
SN - 0277-5387
IS - 20
ER -