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Syntheses and structures of iron(III) complexes of simple N-donor ligands

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Syntheses and structures of iron(III) complexes of simple N-donor ligands. / Cotton, Simon A.; Franckevicius, Vilius; Fawcett, John.
In: Polyhedron, Vol. 21, No. 20, 01.09.2002, p. 2055-2061.

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Cotton SA, Franckevicius V, Fawcett J. Syntheses and structures of iron(III) complexes of simple N-donor ligands. Polyhedron. 2002 Sept 1;21(20):2055-2061. doi: 10.1016/S0277-5387(02)01137-3

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Cotton, Simon A. ; Franckevicius, Vilius ; Fawcett, John. / Syntheses and structures of iron(III) complexes of simple N-donor ligands. In: Polyhedron. 2002 ; Vol. 21, No. 20. pp. 2055-2061.

Bibtex

@article{5dab9b26989e4dd48927f1d0f5899f41,
title = "Syntheses and structures of iron(III) complexes of simple N-donor ligands",
abstract = "Syntheses and structures of mer-[FeCl3(pyrazole)(3)] (1), mer-[FeCl3(N-methylimidazole)(3)] (2), mer-[FeCl3(terpy)] (3) (terpy = 2,2': 6',2{"}-terpyridine), mer-[FeCl3(tptz)] (4) (tptz=2,4,6-tris(2-pyridyl)-1,3,5-triazine) and trans -[FeCl2(3-methylpyrazole)(4)]Cl (5) are reported. The structures demonstrate intramolecular N-H...Cl; imramolecular C-H... Cl; and intermolecular N-H...Cl interactions. Syntheses and analytical data are also reported for [FeCl3(imidazole)(4)] (6), but crystals suitable for X-ray study were not obtained. (C) 2002 Elsevier Science Ltd. All rights reserved.",
keywords = "single-crystal X-ray, SPECTRA, MOLECULAR-STRUCTURE, CRYSTAL, DERIVATIVES, CHLORIDE ALPHA,ALPHA'-DIIMINE SYSTEM, N-donor, CR, terpyridyl, iron(III)",
author = "Cotton, {Simon A.} and Vilius Franckevicius and John Fawcett",
year = "2002",
month = sep,
day = "1",
doi = "10.1016/S0277-5387(02)01137-3",
language = "English",
volume = "21",
pages = "2055--2061",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier Limited",
number = "20",

}

RIS

TY - JOUR

T1 - Syntheses and structures of iron(III) complexes of simple N-donor ligands

AU - Cotton, Simon A.

AU - Franckevicius, Vilius

AU - Fawcett, John

PY - 2002/9/1

Y1 - 2002/9/1

N2 - Syntheses and structures of mer-[FeCl3(pyrazole)(3)] (1), mer-[FeCl3(N-methylimidazole)(3)] (2), mer-[FeCl3(terpy)] (3) (terpy = 2,2': 6',2"-terpyridine), mer-[FeCl3(tptz)] (4) (tptz=2,4,6-tris(2-pyridyl)-1,3,5-triazine) and trans -[FeCl2(3-methylpyrazole)(4)]Cl (5) are reported. The structures demonstrate intramolecular N-H...Cl; imramolecular C-H... Cl; and intermolecular N-H...Cl interactions. Syntheses and analytical data are also reported for [FeCl3(imidazole)(4)] (6), but crystals suitable for X-ray study were not obtained. (C) 2002 Elsevier Science Ltd. All rights reserved.

AB - Syntheses and structures of mer-[FeCl3(pyrazole)(3)] (1), mer-[FeCl3(N-methylimidazole)(3)] (2), mer-[FeCl3(terpy)] (3) (terpy = 2,2': 6',2"-terpyridine), mer-[FeCl3(tptz)] (4) (tptz=2,4,6-tris(2-pyridyl)-1,3,5-triazine) and trans -[FeCl2(3-methylpyrazole)(4)]Cl (5) are reported. The structures demonstrate intramolecular N-H...Cl; imramolecular C-H... Cl; and intermolecular N-H...Cl interactions. Syntheses and analytical data are also reported for [FeCl3(imidazole)(4)] (6), but crystals suitable for X-ray study were not obtained. (C) 2002 Elsevier Science Ltd. All rights reserved.

KW - single-crystal X-ray

KW - SPECTRA

KW - MOLECULAR-STRUCTURE

KW - CRYSTAL

KW - DERIVATIVES

KW - CHLORIDE ALPHA,ALPHA'-DIIMINE SYSTEM

KW - N-donor

KW - CR

KW - terpyridyl

KW - iron(III)

U2 - 10.1016/S0277-5387(02)01137-3

DO - 10.1016/S0277-5387(02)01137-3

M3 - Journal article

VL - 21

SP - 2055

EP - 2061

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 20

ER -