Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
}
TY - JOUR
T1 - Synthesis and vibrational spectra of metal halide complexes of 3,5- lutidine in relation to their structures.
AU - Yurdakul, Senay
AU - Akyüz, Sevim
AU - Davies, J. Eric D.
PY - 1997
Y1 - 1997
N2 - The synthesis and the results of an infrared and Raman spectroscopic study are reported for metal(II) halide 3,5-lutidine (3,5-dimethylpyridine) complexes, M(3,5L)2X2, M = Cd or Zn, X = Cl, Br or I; M = Co, Cu or Hg, X = Cl or Br; M = Mn, Fe or Ni, X = Cl, 3,5L = 3,5-lutidine. Vibrational assignments are given for all the observed bands. Some structure-spectra correlations were found. For a given series of isomorphous complexes the sum of the difference of the values of the vibrational modes of 3,5-lutidine between the free ligand as liquid and the complexed ligand was found to increase in the order of the second ionization potentials of the metals. The frequency shifts were also found to depend on the halogen.
AB - The synthesis and the results of an infrared and Raman spectroscopic study are reported for metal(II) halide 3,5-lutidine (3,5-dimethylpyridine) complexes, M(3,5L)2X2, M = Cd or Zn, X = Cl, Br or I; M = Co, Cu or Hg, X = Cl or Br; M = Mn, Fe or Ni, X = Cl, 3,5L = 3,5-lutidine. Vibrational assignments are given for all the observed bands. Some structure-spectra correlations were found. For a given series of isomorphous complexes the sum of the difference of the values of the vibrational modes of 3,5-lutidine between the free ligand as liquid and the complexed ligand was found to increase in the order of the second ionization potentials of the metals. The frequency shifts were also found to depend on the halogen.
U2 - 10.1080/00945719708000260
DO - 10.1080/00945719708000260
M3 - Journal article
VL - 27
SP - 1235
EP - 1248
JO - Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
JF - Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
IS - 8
ER -