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Synthesis and vibrational spectra of metal halide complexes of 3,5- lutidine in relation to their structures.

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Synthesis and vibrational spectra of metal halide complexes of 3,5- lutidine in relation to their structures. / Yurdakul, Senay; Akyüz, Sevim; Davies, J. Eric D.

In: Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, Vol. 27, No. 8, 1997, p. 1235-1248.

Research output: Contribution to journalJournal articlepeer-review

Harvard

Yurdakul, S, Akyüz, S & Davies, JED 1997, 'Synthesis and vibrational spectra of metal halide complexes of 3,5- lutidine in relation to their structures.', Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, vol. 27, no. 8, pp. 1235-1248. https://doi.org/10.1080/00945719708000260

APA

Yurdakul, S., Akyüz, S., & Davies, J. E. D. (1997). Synthesis and vibrational spectra of metal halide complexes of 3,5- lutidine in relation to their structures. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 27(8), 1235-1248. https://doi.org/10.1080/00945719708000260

Vancouver

Yurdakul S, Akyüz S, Davies JED. Synthesis and vibrational spectra of metal halide complexes of 3,5- lutidine in relation to their structures. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 1997;27(8):1235-1248. https://doi.org/10.1080/00945719708000260

Author

Yurdakul, Senay ; Akyüz, Sevim ; Davies, J. Eric D. / Synthesis and vibrational spectra of metal halide complexes of 3,5- lutidine in relation to their structures. In: Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 1997 ; Vol. 27, No. 8. pp. 1235-1248.

Bibtex

@article{7ad409a8b00f4098a4848674bafce21c,
title = "Synthesis and vibrational spectra of metal halide complexes of 3,5- lutidine in relation to their structures.",
abstract = "The synthesis and the results of an infrared and Raman spectroscopic study are reported for metal(II) halide 3,5-lutidine (3,5-dimethylpyridine) complexes, M(3,5L)2X2, M = Cd or Zn, X = Cl, Br or I; M = Co, Cu or Hg, X = Cl or Br; M = Mn, Fe or Ni, X = Cl, 3,5L = 3,5-lutidine. Vibrational assignments are given for all the observed bands. Some structure-spectra correlations were found. For a given series of isomorphous complexes the sum of the difference of the values of the vibrational modes of 3,5-lutidine between the free ligand as liquid and the complexed ligand was found to increase in the order of the second ionization potentials of the metals. The frequency shifts were also found to depend on the halogen.",
author = "Senay Yurdakul and Sevim Aky{\"u}z and Davies, {J. Eric D.}",
year = "1997",
doi = "10.1080/00945719708000260",
language = "English",
volume = "27",
pages = "1235--1248",
journal = "Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry",
number = "8",

}

RIS

TY - JOUR

T1 - Synthesis and vibrational spectra of metal halide complexes of 3,5- lutidine in relation to their structures.

AU - Yurdakul, Senay

AU - Akyüz, Sevim

AU - Davies, J. Eric D.

PY - 1997

Y1 - 1997

N2 - The synthesis and the results of an infrared and Raman spectroscopic study are reported for metal(II) halide 3,5-lutidine (3,5-dimethylpyridine) complexes, M(3,5L)2X2, M = Cd or Zn, X = Cl, Br or I; M = Co, Cu or Hg, X = Cl or Br; M = Mn, Fe or Ni, X = Cl, 3,5L = 3,5-lutidine. Vibrational assignments are given for all the observed bands. Some structure-spectra correlations were found. For a given series of isomorphous complexes the sum of the difference of the values of the vibrational modes of 3,5-lutidine between the free ligand as liquid and the complexed ligand was found to increase in the order of the second ionization potentials of the metals. The frequency shifts were also found to depend on the halogen.

AB - The synthesis and the results of an infrared and Raman spectroscopic study are reported for metal(II) halide 3,5-lutidine (3,5-dimethylpyridine) complexes, M(3,5L)2X2, M = Cd or Zn, X = Cl, Br or I; M = Co, Cu or Hg, X = Cl or Br; M = Mn, Fe or Ni, X = Cl, 3,5L = 3,5-lutidine. Vibrational assignments are given for all the observed bands. Some structure-spectra correlations were found. For a given series of isomorphous complexes the sum of the difference of the values of the vibrational modes of 3,5-lutidine between the free ligand as liquid and the complexed ligand was found to increase in the order of the second ionization potentials of the metals. The frequency shifts were also found to depend on the halogen.

U2 - 10.1080/00945719708000260

DO - 10.1080/00945719708000260

M3 - Journal article

VL - 27

SP - 1235

EP - 1248

JO - Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry

JF - Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry

IS - 8

ER -