Home > Research > Publications & Outputs > Synthesis, Characterization, Magnetic Propertie...

Research

Links

Text available via DOI:

Keywords

View graph of relations

Synthesis, Characterization, Magnetic Properties, and Topological Aspects of Isoskeletal Heterometallic Hexanuclear CoII4LnIII2 Coordination Clusters Possessing 2,3,4M6–1 Topology

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Published

Standard

Synthesis, Characterization, Magnetic Properties, and Topological Aspects of Isoskeletal Heterometallic Hexanuclear CoII4LnIII2 Coordination Clusters Possessing 2,3,4M6–1 Topology. / Griffiths, Kieran; Novitchi, Ghenadie; Kostakis, George E.
In: European Journal of Inorganic Chemistry, Vol. 2016, No. 17, 22.06.2016, p. 2750-2756.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Griffiths, K, Novitchi, G & Kostakis, GE 2016, 'Synthesis, Characterization, Magnetic Properties, and Topological Aspects of Isoskeletal Heterometallic Hexanuclear CoII4LnIII2 Coordination Clusters Possessing 2,3,4M6–1 Topology', European Journal of Inorganic Chemistry, vol. 2016, no. 17, pp. 2750-2756. https://doi.org/10.1002/ejic.201600078

APA

Griffiths, K., Novitchi, G., & Kostakis, G. E. (2016). Synthesis, Characterization, Magnetic Properties, and Topological Aspects of Isoskeletal Heterometallic Hexanuclear CoII4LnIII2 Coordination Clusters Possessing 2,3,4M6–1 Topology. European Journal of Inorganic Chemistry, 2016(17), 2750-2756. https://doi.org/10.1002/ejic.201600078

Vancouver

Griffiths K, Novitchi G, Kostakis GE. Synthesis, Characterization, Magnetic Properties, and Topological Aspects of Isoskeletal Heterometallic Hexanuclear CoII4LnIII2 Coordination Clusters Possessing 2,3,4M6–1 Topology. European Journal of Inorganic Chemistry. 2016 Jun 22;2016(17):2750-2756. doi: 10.1002/ejic.201600078

Author

Griffiths, Kieran ; Novitchi, Ghenadie ; Kostakis, George E. / Synthesis, Characterization, Magnetic Properties, and Topological Aspects of Isoskeletal Heterometallic Hexanuclear CoII4LnIII2 Coordination Clusters Possessing 2,3,4M6–1 Topology. In: European Journal of Inorganic Chemistry. 2016 ; Vol. 2016, No. 17. pp. 2750-2756.

Bibtex

@article{710a77a9f4594aa79bcdf81da0dfb1a7,
title = "Synthesis, Characterization, Magnetic Properties, and Topological Aspects of Isoskeletal Heterometallic Hexanuclear CoII4LnIII2 Coordination Clusters Possessing 2,3,4M6–1 Topology",
abstract = "The reaction of (E)-2-(2-hydroxy-3-methoxybenzylideneamino)phenol (H2L1) with Co(NO3)26H2O and LnCl3x(H2O) afforded a family of hexanuclear heterometallic coordination clusters (CCs) formulated as [CoII4LnIII2(µ3-OH)2(L1)4Cl2(NO3)2(MeOH)4] 3(Et2O) where Ln is Y (1), Gd (2), Dy (3), and Tb (4). All the compounds are stable in solution as confirmed by ESI-MS studies. The compounds can be described as twisted boat-like and possess a 2,3,4M6–1 topology. The reaction of (E)-2-(5-bromo-2-hydroxy-3-methoxybenzylideneamino)phenol (H2L2) with Co(NO3)26H2O and DyCl3x(H2O) afforded [CoII4DyIII2(µ3-OH)2(L2)4Cl2(NO3)2(MeOH)4] (5), which is isoskeletal to compounds 1–4. Magnetic studies performed over the temperature range 1.8–300 K show that compound 3 undergoes slow magnetic relaxation.",
keywords = "Cobalt, Coordination clusters, Lanthanides, Magnetic properties, Topology",
author = "Kieran Griffiths and Ghenadie Novitchi and Kostakis, {George E.}",
year = "2016",
month = jun,
day = "22",
doi = "10.1002/ejic.201600078",
language = "English",
volume = "2016",
pages = "2750--2756",
journal = "European Journal of Inorganic Chemistry",
issn = "1434-1948",
publisher = "Wiley-VCH Verlag",
number = "17",

}

RIS

TY - JOUR

T1 - Synthesis, Characterization, Magnetic Properties, and Topological Aspects of Isoskeletal Heterometallic Hexanuclear CoII4LnIII2 Coordination Clusters Possessing 2,3,4M6–1 Topology

AU - Griffiths, Kieran

AU - Novitchi, Ghenadie

AU - Kostakis, George E.

PY - 2016/6/22

Y1 - 2016/6/22

N2 - The reaction of (E)-2-(2-hydroxy-3-methoxybenzylideneamino)phenol (H2L1) with Co(NO3)26H2O and LnCl3x(H2O) afforded a family of hexanuclear heterometallic coordination clusters (CCs) formulated as [CoII4LnIII2(µ3-OH)2(L1)4Cl2(NO3)2(MeOH)4] 3(Et2O) where Ln is Y (1), Gd (2), Dy (3), and Tb (4). All the compounds are stable in solution as confirmed by ESI-MS studies. The compounds can be described as twisted boat-like and possess a 2,3,4M6–1 topology. The reaction of (E)-2-(5-bromo-2-hydroxy-3-methoxybenzylideneamino)phenol (H2L2) with Co(NO3)26H2O and DyCl3x(H2O) afforded [CoII4DyIII2(µ3-OH)2(L2)4Cl2(NO3)2(MeOH)4] (5), which is isoskeletal to compounds 1–4. Magnetic studies performed over the temperature range 1.8–300 K show that compound 3 undergoes slow magnetic relaxation.

AB - The reaction of (E)-2-(2-hydroxy-3-methoxybenzylideneamino)phenol (H2L1) with Co(NO3)26H2O and LnCl3x(H2O) afforded a family of hexanuclear heterometallic coordination clusters (CCs) formulated as [CoII4LnIII2(µ3-OH)2(L1)4Cl2(NO3)2(MeOH)4] 3(Et2O) where Ln is Y (1), Gd (2), Dy (3), and Tb (4). All the compounds are stable in solution as confirmed by ESI-MS studies. The compounds can be described as twisted boat-like and possess a 2,3,4M6–1 topology. The reaction of (E)-2-(5-bromo-2-hydroxy-3-methoxybenzylideneamino)phenol (H2L2) with Co(NO3)26H2O and DyCl3x(H2O) afforded [CoII4DyIII2(µ3-OH)2(L2)4Cl2(NO3)2(MeOH)4] (5), which is isoskeletal to compounds 1–4. Magnetic studies performed over the temperature range 1.8–300 K show that compound 3 undergoes slow magnetic relaxation.

KW - Cobalt

KW - Coordination clusters

KW - Lanthanides

KW - Magnetic properties

KW - Topology

U2 - 10.1002/ejic.201600078

DO - 10.1002/ejic.201600078

M3 - Journal article

AN - SCOPUS:84964397328

VL - 2016

SP - 2750

EP - 2756

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 17

ER -