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Synthesis of cobalt phosphides and their application as anodes for lithium ion batteries

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Synthesis of cobalt phosphides and their application as anodes for lithium ion batteries. / Yang, Dan; Zhu, Jixin; Rui, Xianhong et al.
In: ACS Applied Materials and Interfaces, Vol. 5, No. 3, 13.02.2013, p. 1093-1099.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

Harvard

Yang, D, Zhu, J, Rui, X, Tan, H, Cai, R, Hoster, HE, Yu, DYW, Hng, HH & Yan, Q 2013, 'Synthesis of cobalt phosphides and their application as anodes for lithium ion batteries', ACS Applied Materials and Interfaces, vol. 5, no. 3, pp. 1093-1099. https://doi.org/10.1021/am302877q

APA

Yang, D., Zhu, J., Rui, X., Tan, H., Cai, R., Hoster, H. E., Yu, D. Y. W., Hng, H. H., & Yan, Q. (2013). Synthesis of cobalt phosphides and their application as anodes for lithium ion batteries. ACS Applied Materials and Interfaces, 5(3), 1093-1099. https://doi.org/10.1021/am302877q

Vancouver

Yang D, Zhu J, Rui X, Tan H, Cai R, Hoster HE et al. Synthesis of cobalt phosphides and their application as anodes for lithium ion batteries. ACS Applied Materials and Interfaces. 2013 Feb 13;5(3):1093-1099. doi: 10.1021/am302877q

Author

Yang, Dan ; Zhu, Jixin ; Rui, Xianhong et al. / Synthesis of cobalt phosphides and their application as anodes for lithium ion batteries. In: ACS Applied Materials and Interfaces. 2013 ; Vol. 5, No. 3. pp. 1093-1099.

Bibtex

@article{214fae89e4e141a4b9ae20e4f5d29912,
title = "Synthesis of cobalt phosphides and their application as anodes for lithium ion batteries",
abstract = "A facile thermal decomposing method has been developed for the fabrication of CoxP nanostructures with controlled size, phase, and shape (e.g., Co2P rod and spheres, CoP hollow and solid particles). An amorphous carbon layer could be introduced by the carbonization of organic surfactants from the precursors. The electrochemical performance of typical CoP and Co2P samples as anode materials has been investigated and the CoP hollow nanoparticle with carbon coating layer depicts good capacity retention and high rate capability (e.g., specific capacity of 630 mA h g(-1) at 0.2 C after 100 cycles, and a reversible capacity of 256 mA h g(-1) can be achieved at a high current rate of 5 C).",
keywords = "hollow nanoparticles, nanorods, Li storage, cobalt phosphides, oil phase synthesis, IMPROVED ELECTROCHEMICAL PERFORMANCE, NEGATIVE-ELECTRODE, THERMAL-DECOMPOSITION, CONVERSION REACTIONS, NICKEL PHOSPHIDE, SYRINGE PUMP, NANOPARTICLES, TEMPERATURE, NANOWIRES, NANORODS",
author = "Dan Yang and Jixin Zhu and Xianhong Rui and Huiteng Tan and Ren Cai and Hoster, {Harry E.} and Yu, {Denis Y. W.} and Hng, {Huey Hoon} and Qingyu Yan",
year = "2013",
month = feb,
day = "13",
doi = "10.1021/am302877q",
language = "English",
volume = "5",
pages = "1093--1099",
journal = "ACS Applied Materials and Interfaces",
issn = "1944-8244",
publisher = "American Chemical Society",
number = "3",

}

RIS

TY - JOUR

T1 - Synthesis of cobalt phosphides and their application as anodes for lithium ion batteries

AU - Yang, Dan

AU - Zhu, Jixin

AU - Rui, Xianhong

AU - Tan, Huiteng

AU - Cai, Ren

AU - Hoster, Harry E.

AU - Yu, Denis Y. W.

AU - Hng, Huey Hoon

AU - Yan, Qingyu

PY - 2013/2/13

Y1 - 2013/2/13

N2 - A facile thermal decomposing method has been developed for the fabrication of CoxP nanostructures with controlled size, phase, and shape (e.g., Co2P rod and spheres, CoP hollow and solid particles). An amorphous carbon layer could be introduced by the carbonization of organic surfactants from the precursors. The electrochemical performance of typical CoP and Co2P samples as anode materials has been investigated and the CoP hollow nanoparticle with carbon coating layer depicts good capacity retention and high rate capability (e.g., specific capacity of 630 mA h g(-1) at 0.2 C after 100 cycles, and a reversible capacity of 256 mA h g(-1) can be achieved at a high current rate of 5 C).

AB - A facile thermal decomposing method has been developed for the fabrication of CoxP nanostructures with controlled size, phase, and shape (e.g., Co2P rod and spheres, CoP hollow and solid particles). An amorphous carbon layer could be introduced by the carbonization of organic surfactants from the precursors. The electrochemical performance of typical CoP and Co2P samples as anode materials has been investigated and the CoP hollow nanoparticle with carbon coating layer depicts good capacity retention and high rate capability (e.g., specific capacity of 630 mA h g(-1) at 0.2 C after 100 cycles, and a reversible capacity of 256 mA h g(-1) can be achieved at a high current rate of 5 C).

KW - hollow nanoparticles

KW - nanorods

KW - Li storage

KW - cobalt phosphides

KW - oil phase synthesis

KW - IMPROVED ELECTROCHEMICAL PERFORMANCE

KW - NEGATIVE-ELECTRODE

KW - THERMAL-DECOMPOSITION

KW - CONVERSION REACTIONS

KW - NICKEL PHOSPHIDE

KW - SYRINGE PUMP

KW - NANOPARTICLES

KW - TEMPERATURE

KW - NANOWIRES

KW - NANORODS

U2 - 10.1021/am302877q

DO - 10.1021/am302877q

M3 - Journal article

VL - 5

SP - 1093

EP - 1099

JO - ACS Applied Materials and Interfaces

JF - ACS Applied Materials and Interfaces

SN - 1944-8244

IS - 3

ER -