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Synthesis of COF-5 using microwave irradiation and conventional solvothermal routes

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Synthesis of COF-5 using microwave irradiation and conventional solvothermal routes. / Ritchie, Lyndsey K.; Trewin, Abbie; Reguera-Galan, Aida; Hasell, Tom; Cooper, Andrew I.

In: Microporous and Mesoporous Materials, Vol. 132, No. 1-2, 07.2010, p. 132-136.

Research output: Contribution to journalJournal articlepeer-review

Harvard

Ritchie, LK, Trewin, A, Reguera-Galan, A, Hasell, T & Cooper, AI 2010, 'Synthesis of COF-5 using microwave irradiation and conventional solvothermal routes', Microporous and Mesoporous Materials, vol. 132, no. 1-2, pp. 132-136. https://doi.org/10.1016/j.micromeso.2010.02.010

APA

Ritchie, L. K., Trewin, A., Reguera-Galan, A., Hasell, T., & Cooper, A. I. (2010). Synthesis of COF-5 using microwave irradiation and conventional solvothermal routes. Microporous and Mesoporous Materials, 132(1-2), 132-136. https://doi.org/10.1016/j.micromeso.2010.02.010

Vancouver

Ritchie LK, Trewin A, Reguera-Galan A, Hasell T, Cooper AI. Synthesis of COF-5 using microwave irradiation and conventional solvothermal routes. Microporous and Mesoporous Materials. 2010 Jul;132(1-2):132-136. https://doi.org/10.1016/j.micromeso.2010.02.010

Author

Ritchie, Lyndsey K. ; Trewin, Abbie ; Reguera-Galan, Aida ; Hasell, Tom ; Cooper, Andrew I. / Synthesis of COF-5 using microwave irradiation and conventional solvothermal routes. In: Microporous and Mesoporous Materials. 2010 ; Vol. 132, No. 1-2. pp. 132-136.

Bibtex

@article{8183fe9f11aa403887c29bde5817f067,
title = "Synthesis of COF-5 using microwave irradiation and conventional solvothermal routes",
abstract = "A covalent organic framework, COF-5, was synthesized by microwave heating and by conventional solvothermal synthesis. The highest apparent Brunauer-Emmett-Teller surface areas were obtained for materials produced by a combination of microwave heating and microwave extraction. The total surface area for the samples could be sub-divided into external and internal surface areas, arising from the macroscopic morphology and the molecular crystal structure, respectively. Variations in external surface area could be attributed to the different sample morphologies resulting from the various synthesis and purification methods. The experimental internal surface areas correlated well with the simulated Connolly and solvent-accessible surface area (2034 m(2) g(-1) and 1737 m(2) g(-1)). Pore filling simulations can rationalize the stepped gas uptake behavior and identify a physisorbed monolayer followed by filling of the pore interior. This study suggests that microwave irradiation is a convenient alternative route for the synthesis of COF materials, and underlines the importance of considering sample morphology in evaluating surface area data. (C) 2010 Elsevier Inc. All rights reserved.",
keywords = "Microporous materials, Covalent organic networks, COVALENT-ORGANIC FRAMEWORKS, HYDROGEN STORAGE MATERIALS, POLYMER NETWORKS, INTRINSIC MICROPOROSITY, ATOMISTIC SIMULATION, SURFACE-AREAS, ADSORPTION, CRYSTALLINE, CO2",
author = "Ritchie, {Lyndsey K.} and Abbie Trewin and Aida Reguera-Galan and Tom Hasell and Cooper, {Andrew I.}",
year = "2010",
month = jul,
doi = "10.1016/j.micromeso.2010.02.010",
language = "English",
volume = "132",
pages = "132--136",
journal = "Microporous and Mesoporous Materials",
issn = "1387-1811",
publisher = "Elsevier",
number = "1-2",

}

RIS

TY - JOUR

T1 - Synthesis of COF-5 using microwave irradiation and conventional solvothermal routes

AU - Ritchie, Lyndsey K.

AU - Trewin, Abbie

AU - Reguera-Galan, Aida

AU - Hasell, Tom

AU - Cooper, Andrew I.

PY - 2010/7

Y1 - 2010/7

N2 - A covalent organic framework, COF-5, was synthesized by microwave heating and by conventional solvothermal synthesis. The highest apparent Brunauer-Emmett-Teller surface areas were obtained for materials produced by a combination of microwave heating and microwave extraction. The total surface area for the samples could be sub-divided into external and internal surface areas, arising from the macroscopic morphology and the molecular crystal structure, respectively. Variations in external surface area could be attributed to the different sample morphologies resulting from the various synthesis and purification methods. The experimental internal surface areas correlated well with the simulated Connolly and solvent-accessible surface area (2034 m(2) g(-1) and 1737 m(2) g(-1)). Pore filling simulations can rationalize the stepped gas uptake behavior and identify a physisorbed monolayer followed by filling of the pore interior. This study suggests that microwave irradiation is a convenient alternative route for the synthesis of COF materials, and underlines the importance of considering sample morphology in evaluating surface area data. (C) 2010 Elsevier Inc. All rights reserved.

AB - A covalent organic framework, COF-5, was synthesized by microwave heating and by conventional solvothermal synthesis. The highest apparent Brunauer-Emmett-Teller surface areas were obtained for materials produced by a combination of microwave heating and microwave extraction. The total surface area for the samples could be sub-divided into external and internal surface areas, arising from the macroscopic morphology and the molecular crystal structure, respectively. Variations in external surface area could be attributed to the different sample morphologies resulting from the various synthesis and purification methods. The experimental internal surface areas correlated well with the simulated Connolly and solvent-accessible surface area (2034 m(2) g(-1) and 1737 m(2) g(-1)). Pore filling simulations can rationalize the stepped gas uptake behavior and identify a physisorbed monolayer followed by filling of the pore interior. This study suggests that microwave irradiation is a convenient alternative route for the synthesis of COF materials, and underlines the importance of considering sample morphology in evaluating surface area data. (C) 2010 Elsevier Inc. All rights reserved.

KW - Microporous materials

KW - Covalent organic networks

KW - COVALENT-ORGANIC FRAMEWORKS

KW - HYDROGEN STORAGE MATERIALS

KW - POLYMER NETWORKS

KW - INTRINSIC MICROPOROSITY

KW - ATOMISTIC SIMULATION

KW - SURFACE-AREAS

KW - ADSORPTION

KW - CRYSTALLINE

KW - CO2

U2 - 10.1016/j.micromeso.2010.02.010

DO - 10.1016/j.micromeso.2010.02.010

M3 - Journal article

VL - 132

SP - 132

EP - 136

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

SN - 1387-1811

IS - 1-2

ER -