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Synthesis of Cu(I) octamolybdates using tetrakis-acetonitrilecopper(I) hexafluorophosphate

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Synthesis of Cu(I) octamolybdates using tetrakis-acetonitrilecopper(I) hexafluorophosphate. / Fielden, John; Long, De-Liang; Cronin, Leroy et al.
In: Polyhedron, Vol. 28, No. 13, 02.09.2009, p. 2803-2807.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Fielden, J, Long, D-L, Cronin, L & Kögerler, P 2009, 'Synthesis of Cu(I) octamolybdates using tetrakis-acetonitrilecopper(I) hexafluorophosphate', Polyhedron, vol. 28, no. 13, pp. 2803-2807. https://doi.org/10.1016/j.poly.2009.05.058

APA

Fielden, J., Long, D-L., Cronin, L., & Kögerler, P. (2009). Synthesis of Cu(I) octamolybdates using tetrakis-acetonitrilecopper(I) hexafluorophosphate. Polyhedron, 28(13), 2803-2807. https://doi.org/10.1016/j.poly.2009.05.058

Vancouver

Fielden J, Long D-L, Cronin L, Kögerler P. Synthesis of Cu(I) octamolybdates using tetrakis-acetonitrilecopper(I) hexafluorophosphate. Polyhedron. 2009 Sept 2;28(13):2803-2807. doi: 10.1016/j.poly.2009.05.058

Author

Fielden, John ; Long, De-Liang ; Cronin, Leroy et al. / Synthesis of Cu(I) octamolybdates using tetrakis-acetonitrilecopper(I) hexafluorophosphate. In: Polyhedron. 2009 ; Vol. 28, No. 13. pp. 2803-2807.

Bibtex

@article{3f33f447e8664dada69efba61b945aca,
title = "Synthesis of Cu(I) octamolybdates using tetrakis-acetonitrilecopper(I) hexafluorophosphate",
abstract = "Reaction of (NBu4)2[Mo2O7] with [Cu(CH3CN)4](PF6) in acetonitrile results in isolation of the orange β-octamolybdate [Cu(CH3CN)4]2[Mo8O26Cu2(CH3CN)4] (1) along with the colourless α-octamolybdate [Cu(CH3CN)4]4[Mo8O26]·2CH3CN (2). Both products decompose rapidly upon removal from their mother liquors, forming an insoluble, dark brown coloured phase with the composition Cu4[Mo8O26]·0.6CH3CN·16H2O (3). The copper(I) acetonitrile derivatised isopolyanion in 1 thus represents an intermediate structure between the simple, underivatised octamolybdate 2 and fully condensed, polymeric phase 3.",
keywords = "Polyoxometalates, Crystal structure, Copper(I) complex",
author = "John Fielden and De-Liang Long and Leroy Cronin and Paul K{\"o}gerler",
year = "2009",
month = sep,
day = "2",
doi = "10.1016/j.poly.2009.05.058",
language = "English",
volume = "28",
pages = "2803--2807",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier Limited",
number = "13",

}

RIS

TY - JOUR

T1 - Synthesis of Cu(I) octamolybdates using tetrakis-acetonitrilecopper(I) hexafluorophosphate

AU - Fielden, John

AU - Long, De-Liang

AU - Cronin, Leroy

AU - Kögerler, Paul

PY - 2009/9/2

Y1 - 2009/9/2

N2 - Reaction of (NBu4)2[Mo2O7] with [Cu(CH3CN)4](PF6) in acetonitrile results in isolation of the orange β-octamolybdate [Cu(CH3CN)4]2[Mo8O26Cu2(CH3CN)4] (1) along with the colourless α-octamolybdate [Cu(CH3CN)4]4[Mo8O26]·2CH3CN (2). Both products decompose rapidly upon removal from their mother liquors, forming an insoluble, dark brown coloured phase with the composition Cu4[Mo8O26]·0.6CH3CN·16H2O (3). The copper(I) acetonitrile derivatised isopolyanion in 1 thus represents an intermediate structure between the simple, underivatised octamolybdate 2 and fully condensed, polymeric phase 3.

AB - Reaction of (NBu4)2[Mo2O7] with [Cu(CH3CN)4](PF6) in acetonitrile results in isolation of the orange β-octamolybdate [Cu(CH3CN)4]2[Mo8O26Cu2(CH3CN)4] (1) along with the colourless α-octamolybdate [Cu(CH3CN)4]4[Mo8O26]·2CH3CN (2). Both products decompose rapidly upon removal from their mother liquors, forming an insoluble, dark brown coloured phase with the composition Cu4[Mo8O26]·0.6CH3CN·16H2O (3). The copper(I) acetonitrile derivatised isopolyanion in 1 thus represents an intermediate structure between the simple, underivatised octamolybdate 2 and fully condensed, polymeric phase 3.

KW - Polyoxometalates

KW - Crystal structure

KW - Copper(I) complex

U2 - 10.1016/j.poly.2009.05.058

DO - 10.1016/j.poly.2009.05.058

M3 - Journal article

VL - 28

SP - 2803

EP - 2807

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 13

ER -