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Synthesis of Diverse Allylsilanes Employing Brønsted Acid Catalyzed Reductive Functionalization

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Synthesis of Diverse Allylsilanes Employing Brønsted Acid Catalyzed Reductive Functionalization. / Leonard, Elisabeth; Akien, Geoffrey; Britten, Thomas et al.
In: Advanced Synthesis & Catalysis, Vol. 365, No. 22, 21.11.2023, p. 3872-3875.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Leonard, E, Akien, G, Britten, T, Kazi, N, Roberts, D & McLaughlin, M 2023, 'Synthesis of Diverse Allylsilanes Employing Brønsted Acid Catalyzed Reductive Functionalization', Advanced Synthesis & Catalysis, vol. 365, no. 22, pp. 3872-3875. https://doi.org/10.1002/adsc.202300917

APA

Leonard, E., Akien, G., Britten, T., Kazi, N., Roberts, D., & McLaughlin, M. (2023). Synthesis of Diverse Allylsilanes Employing Brønsted Acid Catalyzed Reductive Functionalization. Advanced Synthesis & Catalysis, 365(22), 3872-3875. https://doi.org/10.1002/adsc.202300917

Vancouver

Leonard E, Akien G, Britten T, Kazi N, Roberts D, McLaughlin M. Synthesis of Diverse Allylsilanes Employing Brønsted Acid Catalyzed Reductive Functionalization. Advanced Synthesis & Catalysis. 2023 Nov 21;365(22): 3872-3875. Epub 2023 Nov 6. doi: 10.1002/adsc.202300917

Author

Leonard, Elisabeth ; Akien, Geoffrey ; Britten, Thomas et al. / Synthesis of Diverse Allylsilanes Employing Brønsted Acid Catalyzed Reductive Functionalization. In: Advanced Synthesis & Catalysis. 2023 ; Vol. 365, No. 22. pp. 3872-3875.

Bibtex

@article{1eaad8a9da1e47738d53569b62f6fd15,
title = "Synthesis of Diverse Allylsilanes Employing Br{\o}nsted Acid Catalyzed Reductive Functionalization",
abstract = "We present a rapid (0.25‐1hr), method to produce functionalised allylsilanes from readily available vinylsilanes. Employing a Br{\o}nsted acid catalysed dehydration as the key step, allylsilanes are produced in good yields (22‐98%) and, in most cases, as a single geometric isomer. Furthermore, a possible alkylation‐Cope pathway was discovered for certain substrates and attempts to optimise this are described.",
keywords = "General Chemistry",
author = "Elisabeth Leonard and Geoffrey Akien and Thomas Britten and Nahin Kazi and Dean Roberts and Mark McLaughlin",
year = "2023",
month = nov,
day = "21",
doi = "10.1002/adsc.202300917",
language = "English",
volume = "365",
pages = " 3872--3875",
journal = "Advanced Synthesis & Catalysis",
issn = "1615-4150",
publisher = "Wiley",
number = "22",

}

RIS

TY - JOUR

T1 - Synthesis of Diverse Allylsilanes Employing Brønsted Acid Catalyzed Reductive Functionalization

AU - Leonard, Elisabeth

AU - Akien, Geoffrey

AU - Britten, Thomas

AU - Kazi, Nahin

AU - Roberts, Dean

AU - McLaughlin, Mark

PY - 2023/11/21

Y1 - 2023/11/21

N2 - We present a rapid (0.25‐1hr), method to produce functionalised allylsilanes from readily available vinylsilanes. Employing a Brønsted acid catalysed dehydration as the key step, allylsilanes are produced in good yields (22‐98%) and, in most cases, as a single geometric isomer. Furthermore, a possible alkylation‐Cope pathway was discovered for certain substrates and attempts to optimise this are described.

AB - We present a rapid (0.25‐1hr), method to produce functionalised allylsilanes from readily available vinylsilanes. Employing a Brønsted acid catalysed dehydration as the key step, allylsilanes are produced in good yields (22‐98%) and, in most cases, as a single geometric isomer. Furthermore, a possible alkylation‐Cope pathway was discovered for certain substrates and attempts to optimise this are described.

KW - General Chemistry

U2 - 10.1002/adsc.202300917

DO - 10.1002/adsc.202300917

M3 - Journal article

VL - 365

SP - 3872

EP - 3875

JO - Advanced Synthesis & Catalysis

JF - Advanced Synthesis & Catalysis

SN - 1615-4150

IS - 22

ER -