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Synthesis of glycerol carbonate from dimethyl carbonate and glycerol using CaO derived from eggshells

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Synthesis of glycerol carbonate from dimethyl carbonate and glycerol using CaO derived from eggshells. / Praikaew, Wanichaya; Kiatkittipong, Worapon; Kiatkittipong, Kunlanan et al.
In: MATEC Web of Conferences, Vol. 192, No. 03045, 03045, 14.08.2018.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

Harvard

Praikaew, W, Kiatkittipong, W, Kiatkittipong, K, Laosiripojana, N, iriya-empikul, N, Boonyasuwat, S, Aiouache, F, Najdanovic‐Visak, V & Assabumrungrat, S 2018, 'Synthesis of glycerol carbonate from dimethyl carbonate and glycerol using CaO derived from eggshells', MATEC Web of Conferences, vol. 192, no. 03045, 03045. https://doi.org/10.1051/matecconf/201819203045

APA

Praikaew, W., Kiatkittipong, W., Kiatkittipong, K., Laosiripojana, N., iriya-empikul, N., Boonyasuwat, S., Aiouache, F., Najdanovic‐Visak, V., & Assabumrungrat, S. (2018). Synthesis of glycerol carbonate from dimethyl carbonate and glycerol using CaO derived from eggshells. MATEC Web of Conferences, 192(03045), Article 03045. https://doi.org/10.1051/matecconf/201819203045

Vancouver

Praikaew W, Kiatkittipong W, Kiatkittipong K, Laosiripojana N, iriya-empikul N, Boonyasuwat S et al. Synthesis of glycerol carbonate from dimethyl carbonate and glycerol using CaO derived from eggshells. MATEC Web of Conferences. 2018 Aug 14;192(03045):03045. doi: 10.1051/matecconf/201819203045

Author

Praikaew, Wanichaya ; Kiatkittipong, Worapon ; Kiatkittipong, Kunlanan et al. / Synthesis of glycerol carbonate from dimethyl carbonate and glycerol using CaO derived from eggshells. In: MATEC Web of Conferences. 2018 ; Vol. 192, No. 03045.

Bibtex

@article{cab2eadacd4b46d4bfc4cc715bd0a3f6,
title = "Synthesis of glycerol carbonate from dimethyl carbonate and glycerol using CaO derived from eggshells",
abstract = "Abstract. Waste eggshell is proposed as a highly active catalyst for glycerol carbonate production from dimethyl carbonate (DMC) and glycerol. The effect of reaction temperature, reaction time and catalyst loading on the reaction performance were investigated in order to find a suitable operating condition. CaO derived from waste eggshell exhibits catalytic activity comparable to commercial CaO. By using CaO eggshell, glycerol conversion of 96% can be achieved within 90 min of reaction time under 2.5:1 feed molar ratio of DMC to glycerol, 0.08 mole ratio of CaO to glycerol and reaction temperature of 60°C. The catalyst was examined by XRD, TGA/DSC, SEM, N2 adsorption-desorption and Hammett indicators method.Utilization of eggshell as a catalyst for glycerol carbonate production not only provides a cost-effective and value-added of waste eggshell as a green catalyst, but also decrease amount of waste and its treatment cost which is ecologically friendly",
author = "Wanichaya Praikaew and Worapon Kiatkittipong and Kunlanan Kiatkittipong and Navadol Laosiripojana and Navin iriya-empikul and Sunya Boonyasuwat and Farid Aiouache and Vesna Najdanovic‐Visak and Suttichai Assabumrungrat",
year = "2018",
month = aug,
day = "14",
doi = "10.1051/matecconf/201819203045",
language = "English",
volume = "192",
journal = "MATEC Web of Conferences",
issn = "2261-236X",
publisher = "EDP Sciences",
number = "03045",

}

RIS

TY - JOUR

T1 - Synthesis of glycerol carbonate from dimethyl carbonate and glycerol using CaO derived from eggshells

AU - Praikaew, Wanichaya

AU - Kiatkittipong, Worapon

AU - Kiatkittipong, Kunlanan

AU - Laosiripojana, Navadol

AU - iriya-empikul, Navin

AU - Boonyasuwat, Sunya

AU - Aiouache, Farid

AU - Najdanovic‐Visak, Vesna

AU - Assabumrungrat, Suttichai

PY - 2018/8/14

Y1 - 2018/8/14

N2 - Abstract. Waste eggshell is proposed as a highly active catalyst for glycerol carbonate production from dimethyl carbonate (DMC) and glycerol. The effect of reaction temperature, reaction time and catalyst loading on the reaction performance were investigated in order to find a suitable operating condition. CaO derived from waste eggshell exhibits catalytic activity comparable to commercial CaO. By using CaO eggshell, glycerol conversion of 96% can be achieved within 90 min of reaction time under 2.5:1 feed molar ratio of DMC to glycerol, 0.08 mole ratio of CaO to glycerol and reaction temperature of 60°C. The catalyst was examined by XRD, TGA/DSC, SEM, N2 adsorption-desorption and Hammett indicators method.Utilization of eggshell as a catalyst for glycerol carbonate production not only provides a cost-effective and value-added of waste eggshell as a green catalyst, but also decrease amount of waste and its treatment cost which is ecologically friendly

AB - Abstract. Waste eggshell is proposed as a highly active catalyst for glycerol carbonate production from dimethyl carbonate (DMC) and glycerol. The effect of reaction temperature, reaction time and catalyst loading on the reaction performance were investigated in order to find a suitable operating condition. CaO derived from waste eggshell exhibits catalytic activity comparable to commercial CaO. By using CaO eggshell, glycerol conversion of 96% can be achieved within 90 min of reaction time under 2.5:1 feed molar ratio of DMC to glycerol, 0.08 mole ratio of CaO to glycerol and reaction temperature of 60°C. The catalyst was examined by XRD, TGA/DSC, SEM, N2 adsorption-desorption and Hammett indicators method.Utilization of eggshell as a catalyst for glycerol carbonate production not only provides a cost-effective and value-added of waste eggshell as a green catalyst, but also decrease amount of waste and its treatment cost which is ecologically friendly

U2 - 10.1051/matecconf/201819203045

DO - 10.1051/matecconf/201819203045

M3 - Journal article

VL - 192

JO - MATEC Web of Conferences

JF - MATEC Web of Conferences

SN - 2261-236X

IS - 03045

M1 - 03045

ER -