Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - THE EFFECTS OF ALLYL ETHERS UPON RADICAL POLYMERIZATIONS.
AU - Bevington, J. C.
AU - Huckerby, T. N.
AU - Hunt, B. J.
AU - Jenkins, A. D.
PY - 2001
Y1 - 2001
N2 - Three allyl ethers, viz. the ethyl, 2-hydroxyethyl and phenyl compounds, have been examined as additives in radical polymerizations of styrene (STY), methyl methacrylate (MMA) and acrylonitrile (ACN) at 60°C using azobisisobutyronitrile as initiator. As retarders and transfer agents, the ethers are considerably more effective with ACN than with the other monomers. Allyl phenyl ether engages in significant copolymerization with ACN and slight copolymerization with MMA; there is negligible incorporation in polySTY.
AB - Three allyl ethers, viz. the ethyl, 2-hydroxyethyl and phenyl compounds, have been examined as additives in radical polymerizations of styrene (STY), methyl methacrylate (MMA) and acrylonitrile (ACN) at 60°C using azobisisobutyronitrile as initiator. As retarders and transfer agents, the ethers are considerably more effective with ACN than with the other monomers. Allyl phenyl ether engages in significant copolymerization with ACN and slight copolymerization with MMA; there is negligible incorporation in polySTY.
KW - Radical polymerization
KW - Allyl ethers
KW - Retardation
KW - Transfer
U2 - 10.1081/MA-100103869
DO - 10.1081/MA-100103869
M3 - Journal article
VL - 38
SP - 627
EP - 640
JO - Journal of Macromolecular Science Part A Pure and Applied Chemistry
JF - Journal of Macromolecular Science Part A Pure and Applied Chemistry
SN - 1060-1325
IS - 7
ER -