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The Electrochemical Characterization of Functionalized Isoindolinones

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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The Electrochemical Characterization of Functionalized Isoindolinones. / Smith, Daniel. E.; Basson, Ashley J.; Owen, Niamh J. et al.
In: ChemElectroChem, Vol. 12, No. 12, e202500044, 10.06.2025.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Smith, DE, Basson, AJ, Owen, NJ, Potter, M, McLaughlin, MG & Toghill, KE 2025, 'The Electrochemical Characterization of Functionalized Isoindolinones', ChemElectroChem, vol. 12, no. 12, e202500044. https://doi.org/10.1002/celc.202500044

APA

Smith, D. E., Basson, A. J., Owen, N. J., Potter, M., McLaughlin, M. G., & Toghill, K. E. (2025). The Electrochemical Characterization of Functionalized Isoindolinones. ChemElectroChem, 12(12), Article e202500044. https://doi.org/10.1002/celc.202500044

Vancouver

Smith DE, Basson AJ, Owen NJ, Potter M, McLaughlin MG, Toghill KE. The Electrochemical Characterization of Functionalized Isoindolinones. ChemElectroChem. 2025 Jun 10;12(12):e202500044. Epub 2025 May 27. doi: 10.1002/celc.202500044

Author

Smith, Daniel. E. ; Basson, Ashley J. ; Owen, Niamh J. et al. / The Electrochemical Characterization of Functionalized Isoindolinones. In: ChemElectroChem. 2025 ; Vol. 12, No. 12.

Bibtex

@article{4e9ef2c5087f4b9baa83580af27963b3,
title = "The Electrochemical Characterization of Functionalized Isoindolinones",
abstract = "This study considers the electrochemical and physical properties of six functionalized isoindolinones, synthesized using a facile, green route. The compounds show redox activity at a highly negative potential with quasireversible redox potentials of ≈−2.8 V versus Fc/Fc+, a potential in the region of alkali metal deposition and intercalation. For those molecules with a specific structural motif, the electrochemical behavior is electrochemically quasireversible, attributed to the formation of a carbanion radical stabilized on the carbonyl group. The electrochemical properties of the reversible compounds are assessed, with the lead‐performing compound extensively characterized galvanostatically to assess its candidacy for nonaqueous, high‐voltage energy storage.",
keywords = "voltammetry, reactive intermediates, molecular electrochemistry, energy storage, redoxmers",
author = "Smith, {Daniel. E.} and Basson, {Ashley J.} and Owen, {Niamh J.} and Mark Potter and McLaughlin, {Mark G.} and Toghill, {Kathryn E.}",
year = "2025",
month = jun,
day = "10",
doi = "10.1002/celc.202500044",
language = "English",
volume = "12",
journal = "ChemElectroChem",
issn = "2196-0216",
publisher = "John Wiley and Sons Ltd",
number = "12",

}

RIS

TY - JOUR

T1 - The Electrochemical Characterization of Functionalized Isoindolinones

AU - Smith, Daniel. E.

AU - Basson, Ashley J.

AU - Owen, Niamh J.

AU - Potter, Mark

AU - McLaughlin, Mark G.

AU - Toghill, Kathryn E.

PY - 2025/6/10

Y1 - 2025/6/10

N2 - This study considers the electrochemical and physical properties of six functionalized isoindolinones, synthesized using a facile, green route. The compounds show redox activity at a highly negative potential with quasireversible redox potentials of ≈−2.8 V versus Fc/Fc+, a potential in the region of alkali metal deposition and intercalation. For those molecules with a specific structural motif, the electrochemical behavior is electrochemically quasireversible, attributed to the formation of a carbanion radical stabilized on the carbonyl group. The electrochemical properties of the reversible compounds are assessed, with the lead‐performing compound extensively characterized galvanostatically to assess its candidacy for nonaqueous, high‐voltage energy storage.

AB - This study considers the electrochemical and physical properties of six functionalized isoindolinones, synthesized using a facile, green route. The compounds show redox activity at a highly negative potential with quasireversible redox potentials of ≈−2.8 V versus Fc/Fc+, a potential in the region of alkali metal deposition and intercalation. For those molecules with a specific structural motif, the electrochemical behavior is electrochemically quasireversible, attributed to the formation of a carbanion radical stabilized on the carbonyl group. The electrochemical properties of the reversible compounds are assessed, with the lead‐performing compound extensively characterized galvanostatically to assess its candidacy for nonaqueous, high‐voltage energy storage.

KW - voltammetry

KW - reactive intermediates

KW - molecular electrochemistry

KW - energy storage

KW - redoxmers

U2 - 10.1002/celc.202500044

DO - 10.1002/celc.202500044

M3 - Journal article

VL - 12

JO - ChemElectroChem

JF - ChemElectroChem

SN - 2196-0216

IS - 12

M1 - e202500044

ER -