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The hydrolysis of hydroxamic acid complexants in the presence of non-oxidizing metal ions 2: Neptunium (IV) ions.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

<mark>Journal publication date</mark>02/2008
<mark>Journal</mark>Journal of Solution Chemistry
Issue number2
Number of pages18
Pages (from-to)215-232
Publication StatusPublished
<mark>Original language</mark>English


Hydroxamic acids are salt free, organic compounds with affinities for cations such as Fe3+, Np4+ and Pu4+, and have been identified as suitable reagents for the control of Pu and Np in advanced nuclear fuel reprocessing. The results of a UV-visible, near-IR spectrophotometric study of the 1:1 and 2:1 complexes formed between formo- and aceto-hydroxamic acids (FHA, AHA) and Np(IV) ions are interpreted using speciation diagrams for the identification of the species present at different pH and ligand to metal ratios. A kinetic model that describes the instability of the complex due to hydrolysis of the hydroxamate moiety, previously developed for the Fe(III)-AHA complexes (Andrieux et al. in J. Solution Chem. 36:1201-1217, [2007]), is tested here against experimental Np(IV)-FHA data. Consequently, the complexation constant for formation of the 1:1 Np(IV)-FHA complex in nitric acid is estimated at K-1=2715 and indications are that complexation protects the ligand against hydrolysis at 0.1 > pH >-0.1.

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The original publication is available at www.springerlink.com