The mass of ²³⁵ U present in storage cylinders containing low enriched uranium (LEU) in the form of uranium hexafluoride (UF ₆) may be verified nondestructively using a combination of gamma-ray based enrichment meter and passive neutron counting techniques. A hypothetical concern is that the (α,n) production rate in aged bulk UF ₆ might differ from that of fresh material if the chemical composition changes over time, the thought being that this could be initiated by the self-induced radiation field, the process known as radiolysis. To support the physics-based interpretation of the observations Croft et al. measured, in 2020, for the specific ²³⁴ U-driven (α,n)-yield in UF ₆, this work reviews available literature to quantify the possible impact of radiolysis on (α,n) production rate. Building on the review, a radiochemical yield value, G = 0.5 molecules of F ₂ per 100 eV is selected, to calculate the impact of UF5 production – via radiolysis – on the (α,n)-yield. Calculations demonstrate a negligible impact on bulk UF ₆ concentration and respective neutron yield.