Final published version
Research output: Contribution to Journal/Magazine › Journal article › peer-review
<mark>Journal publication date</mark> | 1/03/2005 |
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<mark>Journal</mark> | Inorganica Chimica Acta |
Issue number | 4 |
Volume | 358 |
Number of pages | 10 |
Pages (from-to) | 1079-1088 |
Publication Status | Published |
<mark>Original language</mark> | English |
Tris-chelate 5-hydroxymethyl-2,2′-bipyridine complexes of ruthenium (II) and the structurally related benzo- and naphthoesters have been isolated. The mer-isomer of the alcohol functionalised complex has been isolated by selective precipitation from methylene chloride and was subsequently functionalised to the benzoester with retention of the geometrical isomerism. The fac- and mer-isomeric forms of the ester complexes were separated using preparative plate silica chromatography and characterised by 1H NMR spectroscopy. X-ray structural analysis of the fac-isomer of both the ester complexes confirmed the product assignment. The photophysical properties of the three isomers were investigated, indicating very similar absorption spectra to [Ru(bipy)3]2+. The emission wavelength was comparable in each case, with the aromatic ester complexes giving a much longer lifetime and higher quantum yields