The non-enzymatic determination of glucose using an electrolytically fabricated nickel microparticle modified boron-doped diamond electrode or nickel foil electrode

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The non-enzymatic determination of glucose using an electrolytically fabricated nickel microparticle modified boron-doped diamond electrode or nickel foil electrode. / Toghill, Kathryn E.; Xiao, Lei; Phillips, Michael A. et al.

In: Sensors and Actuators B: Chemical, Vol. 147, No. 2, 03.06.2010, p. 642-652.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Bibtex

@article{eef29f2cae4a4af0bf6f66eb3a7ef182,

title = "The non-enzymatic determination of glucose using an electrolytically fabricated nickel microparticle modified boron-doped diamond electrode or nickel foil electrode",

abstract = "A nickel modified boron-doped diamond (Ni-BDD) electrode or nickel foil electrode were used in the nonenzymatic determination of glucose in alkaline solutions. The Ni-BDD electrode was electrodeposited from a 1 mM Ni(NO(3))(2) solution (pH 5), followed by repeat cycling in KOH. Subsequent analysis utilised the Ni(OH)(2)/NiOOH redox couple to electrocatalyse the oxidation of glucose.Glucose was determined to limits of 2.7 mu M with a sensitivity of 1.04 mu A mu M(-1) cm(-2) at the Ni-BDD electrode. The foil electrode was comparably sensitive achieving a limit of 1.8 mu M but a relatively lower sensitivity of 0.67 mu A mu M(-1) cm(-2). SEM analysis of the electrodes found the Ni-BDD to be modified by a quasi-random microparticle assembly, with approximately 7.6 mu g cm(-2) of nickel present on the surface. (C) 2010 Elsevier B.V. All rights reserved.",

keywords = "Nickel, Microparticles, Boron-doped diamond, Electrocatalysis, Glucose, Non-enzymatic, GLASSY-CARBON ELECTRODE, NANOPOROUS PLATINUM-ELECTRODES, NANOTUBE HYBRID NANOSTRUCTURES, CHEMICALLY-MODIFIED ELECTRODE, FLOW-INJECTION ANALYSIS, THIN-FILM ELECTRODES, ELECTROCHEMICAL DETECTION, LIQUID-CHROMATOGRAPHY, ELECTROCATALYTIC OXIDATION, ALLOY ELECTRODE",

author = "Toghill, {Kathryn E.} and Lei Xiao and Phillips, {Michael A.} and Compton, {Richard G.}",

year = "2010",

month = jun,

day = "3",

doi = "10.1016/j.snb.2010.03.091",

language = "English",

volume = "147",

pages = "642--652",

journal = "Sensors and Actuators B: Chemical",

issn = "0925-4005",

publisher = "Elsevier",

number = "2",

}

RIS

TY - JOUR

T1 - The non-enzymatic determination of glucose using an electrolytically fabricated nickel microparticle modified boron-doped diamond electrode or nickel foil electrode

AU - Toghill, Kathryn E.

AU - Xiao, Lei

AU - Phillips, Michael A.

AU - Compton, Richard G.

PY - 2010/6/3

Y1 - 2010/6/3

N2 - A nickel modified boron-doped diamond (Ni-BDD) electrode or nickel foil electrode were used in the nonenzymatic determination of glucose in alkaline solutions. The Ni-BDD electrode was electrodeposited from a 1 mM Ni(NO(3))(2) solution (pH 5), followed by repeat cycling in KOH. Subsequent analysis utilised the Ni(OH)(2)/NiOOH redox couple to electrocatalyse the oxidation of glucose.Glucose was determined to limits of 2.7 mu M with a sensitivity of 1.04 mu A mu M(-1) cm(-2) at the Ni-BDD electrode. The foil electrode was comparably sensitive achieving a limit of 1.8 mu M but a relatively lower sensitivity of 0.67 mu A mu M(-1) cm(-2). SEM analysis of the electrodes found the Ni-BDD to be modified by a quasi-random microparticle assembly, with approximately 7.6 mu g cm(-2) of nickel present on the surface. (C) 2010 Elsevier B.V. All rights reserved.

AB - A nickel modified boron-doped diamond (Ni-BDD) electrode or nickel foil electrode were used in the nonenzymatic determination of glucose in alkaline solutions. The Ni-BDD electrode was electrodeposited from a 1 mM Ni(NO(3))(2) solution (pH 5), followed by repeat cycling in KOH. Subsequent analysis utilised the Ni(OH)(2)/NiOOH redox couple to electrocatalyse the oxidation of glucose.Glucose was determined to limits of 2.7 mu M with a sensitivity of 1.04 mu A mu M(-1) cm(-2) at the Ni-BDD electrode. The foil electrode was comparably sensitive achieving a limit of 1.8 mu M but a relatively lower sensitivity of 0.67 mu A mu M(-1) cm(-2). SEM analysis of the electrodes found the Ni-BDD to be modified by a quasi-random microparticle assembly, with approximately 7.6 mu g cm(-2) of nickel present on the surface. (C) 2010 Elsevier B.V. All rights reserved.

KW - Nickel

KW - Microparticles

KW - Boron-doped diamond

KW - Electrocatalysis

KW - Glucose

KW - Non-enzymatic

KW - GLASSY-CARBON ELECTRODE

KW - NANOPOROUS PLATINUM-ELECTRODES

KW - NANOTUBE HYBRID NANOSTRUCTURES

KW - CHEMICALLY-MODIFIED ELECTRODE

KW - FLOW-INJECTION ANALYSIS

KW - THIN-FILM ELECTRODES

KW - ELECTROCHEMICAL DETECTION

KW - LIQUID-CHROMATOGRAPHY

KW - ELECTROCATALYTIC OXIDATION

KW - ALLOY ELECTRODE

U2 - 10.1016/j.snb.2010.03.091

DO - 10.1016/j.snb.2010.03.091

M3 - Journal article

VL - 147

SP - 642

EP - 652

JO - Sensors and Actuators B: Chemical

JF - Sensors and Actuators B: Chemical

SN - 0925-4005

IS - 2

ER -

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