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The role of Sb5+ in the structure of Sb2O 3-B2O3 binary glasses - An NMR and Mössbauer spectroscopy study

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The role of Sb5+ in the structure of Sb2O 3-B2O3 binary glasses - An NMR and Mössbauer spectroscopy study. / Holland, D.; Hannon, A.C.; Smith, M.E. et al.
In: Solid State Nuclear Magnetic Resonance, Vol. 26, No. 3-4 SPEC. ISS., 11.2004, p. 172-179.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Holland, D, Hannon, AC, Smith, ME, Johnson, CE, Thomas, MF & Beesley, AM 2004, 'The role of Sb5+ in the structure of Sb2O 3-B2O3 binary glasses - An NMR and Mössbauer spectroscopy study', Solid State Nuclear Magnetic Resonance, vol. 26, no. 3-4 SPEC. ISS., pp. 172-179. https://doi.org/10.1016/j.ssnmr.2004.02.004

APA

Holland, D., Hannon, A. C., Smith, M. E., Johnson, C. E., Thomas, M. F., & Beesley, A. M. (2004). The role of Sb5+ in the structure of Sb2O 3-B2O3 binary glasses - An NMR and Mössbauer spectroscopy study. Solid State Nuclear Magnetic Resonance, 26(3-4 SPEC. ISS.), 172-179. https://doi.org/10.1016/j.ssnmr.2004.02.004

Vancouver

Holland D, Hannon AC, Smith ME, Johnson CE, Thomas MF, Beesley AM. The role of Sb5+ in the structure of Sb2O 3-B2O3 binary glasses - An NMR and Mössbauer spectroscopy study. Solid State Nuclear Magnetic Resonance. 2004 Nov;26(3-4 SPEC. ISS.):172-179. doi: 10.1016/j.ssnmr.2004.02.004

Author

Holland, D. ; Hannon, A.C. ; Smith, M.E. et al. / The role of Sb5+ in the structure of Sb2O 3-B2O3 binary glasses - An NMR and Mössbauer spectroscopy study. In: Solid State Nuclear Magnetic Resonance. 2004 ; Vol. 26, No. 3-4 SPEC. ISS. pp. 172-179.

Bibtex

@article{5ff412e6c0b04ee6bc15854988361a25,
title = "The role of Sb5+ in the structure of Sb2O 3-B2O3 binary glasses - An NMR and M{\"o}ssbauer spectroscopy study",
abstract = "Glasses of general formula xSb2O3 (1-x)B 2O3 (0≤x≤0.8) have been prepared by conventional melt- quenching. M{\"o}ssbauer spectroscopy shows that a fraction of the Sb3+ is converted to Sb5+ and this fraction increases with x. High-field 11B MAS NMR gives well-resolved resonances from boron atoms which are 3- and 4-coordinated to oxygen. The fraction of 4-coordinated boron, N4, goes through a maximum value of 0.12±0.01 at x=0.5. The position of the maximum in N4 is consistent with the cation potential for Sb3+, as observed for other systems. However, the low value of N4 at this maximum is not so readily explained. The values are similar to those predicted if [BO 4]- were stabilised by [SbO4]+ but the trends with composition are different. {\textcopyright} 2004 Elsevier Inc. All rights reserved.",
keywords = "Antimony, Borate, Glass, MAS NMR, M{\"o}ssbauer spectroscopy, Boron, Melting, Molecular structure, Molecular vibrations, Nuclear magnetic resonance spectroscopy, Positive ions, Quenching, Binary glasses, Melt-quenching",
author = "D. Holland and A.C. Hannon and M.E. Smith and C.E. Johnson and M.F. Thomas and A.M. Beesley",
year = "2004",
month = nov,
doi = "10.1016/j.ssnmr.2004.02.004",
language = "English",
volume = "26",
pages = "172--179",
journal = "Solid State Nuclear Magnetic Resonance",
issn = "0926-2040",
publisher = "ACADEMIC PRESS INC ELSEVIER SCIENCE",
number = "3-4 SPEC. ISS.",

}

RIS

TY - JOUR

T1 - The role of Sb5+ in the structure of Sb2O 3-B2O3 binary glasses - An NMR and Mössbauer spectroscopy study

AU - Holland, D.

AU - Hannon, A.C.

AU - Smith, M.E.

AU - Johnson, C.E.

AU - Thomas, M.F.

AU - Beesley, A.M.

PY - 2004/11

Y1 - 2004/11

N2 - Glasses of general formula xSb2O3 (1-x)B 2O3 (0≤x≤0.8) have been prepared by conventional melt- quenching. Mössbauer spectroscopy shows that a fraction of the Sb3+ is converted to Sb5+ and this fraction increases with x. High-field 11B MAS NMR gives well-resolved resonances from boron atoms which are 3- and 4-coordinated to oxygen. The fraction of 4-coordinated boron, N4, goes through a maximum value of 0.12±0.01 at x=0.5. The position of the maximum in N4 is consistent with the cation potential for Sb3+, as observed for other systems. However, the low value of N4 at this maximum is not so readily explained. The values are similar to those predicted if [BO 4]- were stabilised by [SbO4]+ but the trends with composition are different. © 2004 Elsevier Inc. All rights reserved.

AB - Glasses of general formula xSb2O3 (1-x)B 2O3 (0≤x≤0.8) have been prepared by conventional melt- quenching. Mössbauer spectroscopy shows that a fraction of the Sb3+ is converted to Sb5+ and this fraction increases with x. High-field 11B MAS NMR gives well-resolved resonances from boron atoms which are 3- and 4-coordinated to oxygen. The fraction of 4-coordinated boron, N4, goes through a maximum value of 0.12±0.01 at x=0.5. The position of the maximum in N4 is consistent with the cation potential for Sb3+, as observed for other systems. However, the low value of N4 at this maximum is not so readily explained. The values are similar to those predicted if [BO 4]- were stabilised by [SbO4]+ but the trends with composition are different. © 2004 Elsevier Inc. All rights reserved.

KW - Antimony

KW - Borate

KW - Glass

KW - MAS NMR

KW - Mössbauer spectroscopy

KW - Boron

KW - Melting

KW - Molecular structure

KW - Molecular vibrations

KW - Nuclear magnetic resonance spectroscopy

KW - Positive ions

KW - Quenching

KW - Binary glasses

KW - Melt-quenching

U2 - 10.1016/j.ssnmr.2004.02.004

DO - 10.1016/j.ssnmr.2004.02.004

M3 - Journal article

VL - 26

SP - 172

EP - 179

JO - Solid State Nuclear Magnetic Resonance

JF - Solid State Nuclear Magnetic Resonance

SN - 0926-2040

IS - 3-4 SPEC. ISS.

ER -