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The synthesis of Ru(diene)2P(OMe)3 complexes and the formation of 3:3-octadienediyl or 4-octatriene ligands upon phosphite addition to M(dimethylbutadiene)2CO (M=Fe, Ru).

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<mark>Journal publication date</mark>8/03/1988
<mark>Journal</mark>Journal of Organometallic Chemistry
Issue number1
Volume342
Number of pages9
Pages (from-to)87-95
Publication StatusPublished
<mark>Original language</mark>English

Abstract

Low temperature addition of P(OMe)3 to Ru/2,3-dimethylbutadiene and Ru/1,3-cyclohexadiene cocondensates yields Ru(diene)2P(OMe)3 complexes. The reactions of the bis(dimethylbutadiene) complexes M(C6H10)CO (M  Fe, Ru) with P(OMe)3 give new complexes containing either η3:η3-octadienediyl or η4-octatriene ligands.