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Thermodynamic analysis of glycerin steam reforming

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Thermodynamic analysis of glycerin steam reforming. / Wang, Xiaodong; Li, S.; Wang, H. et al.
In: Energy and Fuels, Vol. 22, No. 6, 2008, p. 4285-4291.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Wang, X, Li, S, Wang, H, Liu, B & Ma, X 2008, 'Thermodynamic analysis of glycerin steam reforming', Energy and Fuels, vol. 22, no. 6, pp. 4285-4291. https://doi.org/10.1021/ef800487r

APA

Wang, X., Li, S., Wang, H., Liu, B., & Ma, X. (2008). Thermodynamic analysis of glycerin steam reforming. Energy and Fuels, 22(6), 4285-4291. https://doi.org/10.1021/ef800487r

Vancouver

Wang X, Li S, Wang H, Liu B, Ma X. Thermodynamic analysis of glycerin steam reforming. Energy and Fuels. 2008;22(6):4285-4291. doi: 10.1021/ef800487r

Author

Wang, Xiaodong ; Li, S. ; Wang, H. et al. / Thermodynamic analysis of glycerin steam reforming. In: Energy and Fuels. 2008 ; Vol. 22, No. 6. pp. 4285-4291.

Bibtex

@article{ec4fa4a5df8c4e17a677526b9c8686c4,
title = "Thermodynamic analysis of glycerin steam reforming",
abstract = "Thermodynamic properties of glycerin steam reforming have been studied with the method of Gibbs free energy minimization for hydrogen and/or synthesis gas production. Equilibrium compositions including the coke-formed and coke-free regions were determined as a function of water/glycerin molar ratios (1:1−12:1) and reforming temperatures (550−1200 K) at different pressures (1−50 atm). Optimum conditions for hydrogen production are temperatures between 925 and 975 K and water/glycerin ratios of 9−12 at atmospheric pressure, whereas temperatures above 1035 K and water/glycerin ratios between 2 and 3 at 20−50 atm are suitable for the production of synthesis gas that favors both methanol synthesis and low-temperature Fischer−Tropsch synthesis. However, synthesis gas obtained from glycerin steam reforming is not feasible for direct use in high-temperature Fischer−Tropsch synthesis. Under these optimum conditions, carbon formation can be thermodynamically inhibited.",
author = "Xiaodong Wang and S. Li and H. Wang and B. Liu and X. Ma",
year = "2008",
doi = "10.1021/ef800487r",
language = "English",
volume = "22",
pages = "4285--4291",
journal = "Energy and Fuels",
issn = "0887-0624",
publisher = "American Chemical Society",
number = "6",

}

RIS

TY - JOUR

T1 - Thermodynamic analysis of glycerin steam reforming

AU - Wang, Xiaodong

AU - Li, S.

AU - Wang, H.

AU - Liu, B.

AU - Ma, X.

PY - 2008

Y1 - 2008

N2 - Thermodynamic properties of glycerin steam reforming have been studied with the method of Gibbs free energy minimization for hydrogen and/or synthesis gas production. Equilibrium compositions including the coke-formed and coke-free regions were determined as a function of water/glycerin molar ratios (1:1−12:1) and reforming temperatures (550−1200 K) at different pressures (1−50 atm). Optimum conditions for hydrogen production are temperatures between 925 and 975 K and water/glycerin ratios of 9−12 at atmospheric pressure, whereas temperatures above 1035 K and water/glycerin ratios between 2 and 3 at 20−50 atm are suitable for the production of synthesis gas that favors both methanol synthesis and low-temperature Fischer−Tropsch synthesis. However, synthesis gas obtained from glycerin steam reforming is not feasible for direct use in high-temperature Fischer−Tropsch synthesis. Under these optimum conditions, carbon formation can be thermodynamically inhibited.

AB - Thermodynamic properties of glycerin steam reforming have been studied with the method of Gibbs free energy minimization for hydrogen and/or synthesis gas production. Equilibrium compositions including the coke-formed and coke-free regions were determined as a function of water/glycerin molar ratios (1:1−12:1) and reforming temperatures (550−1200 K) at different pressures (1−50 atm). Optimum conditions for hydrogen production are temperatures between 925 and 975 K and water/glycerin ratios of 9−12 at atmospheric pressure, whereas temperatures above 1035 K and water/glycerin ratios between 2 and 3 at 20−50 atm are suitable for the production of synthesis gas that favors both methanol synthesis and low-temperature Fischer−Tropsch synthesis. However, synthesis gas obtained from glycerin steam reforming is not feasible for direct use in high-temperature Fischer−Tropsch synthesis. Under these optimum conditions, carbon formation can be thermodynamically inhibited.

U2 - 10.1021/ef800487r

DO - 10.1021/ef800487r

M3 - Journal article

VL - 22

SP - 4285

EP - 4291

JO - Energy and Fuels

JF - Energy and Fuels

SN - 0887-0624

IS - 6

ER -