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Thermodynamic analysis of hydrogen production from glycerol autothermal reforming

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Thermodynamic analysis of hydrogen production from glycerol autothermal reforming. / Wang, H.; Wang, Xiaodong; Li, M. et al.
In: International Journal of Hydrogen Energy, Vol. 34, No. 14, 2009, p. 5683-5690.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Wang, H, Wang, X, Li, M, Li, S, Wang, S & Ma, X 2009, 'Thermodynamic analysis of hydrogen production from glycerol autothermal reforming', International Journal of Hydrogen Energy, vol. 34, no. 14, pp. 5683-5690. https://doi.org/10.1016/j.ijhydene.2009.05.118

APA

Wang, H., Wang, X., Li, M., Li, S., Wang, S., & Ma, X. (2009). Thermodynamic analysis of hydrogen production from glycerol autothermal reforming. International Journal of Hydrogen Energy, 34(14), 5683-5690. https://doi.org/10.1016/j.ijhydene.2009.05.118

Vancouver

Wang H, Wang X, Li M, Li S, Wang S, Ma X. Thermodynamic analysis of hydrogen production from glycerol autothermal reforming. International Journal of Hydrogen Energy. 2009;34(14):5683-5690. doi: 10.1016/j.ijhydene.2009.05.118

Author

Wang, H. ; Wang, Xiaodong ; Li, M. et al. / Thermodynamic analysis of hydrogen production from glycerol autothermal reforming. In: International Journal of Hydrogen Energy. 2009 ; Vol. 34, No. 14. pp. 5683-5690.

Bibtex

@article{1e872a841ac44badb62e947987bac99a,
title = "Thermodynamic analysis of hydrogen production from glycerol autothermal reforming",
abstract = "In this work, thermodynamics was applied to investigate the glycerol autothermal reforming to generate hydrogen for fuel cell application. Equilibrium calculations employing the Gibbs free energy minimization were performed in a wide range of temperature (700–1000 K), steam to glycerol ratio (1–12) and oxygen to glycerol ratio (0.0–3.0). Results show that the most favorable conditions for hydrogen production are achieved with the temperatures, steam to glycerol ratios and oxygen to glycerol ratios of 900–1000 K, 9–12 and 0.0–0.4, respectively. Further, it is demonstrated that thermoneutral conditions (steam to glycerol ratio 9–12) can be obtained at oxygen to glycerol ratios of around 0.36 (at 900 K) and 0.38–0.39 (at 1000 K). Under these thermoneutral conditions, the maximum number of moles of hydrogen produced are 5.62 (900 K) and 5.43 (1000 K) with a steam to glycerol ratio of 12. Also, it should be noted that methane and carbon formation can be effectively eliminated.",
author = "H. Wang and Xiaodong Wang and M. Li and S. Li and S. Wang and X. Ma",
year = "2009",
doi = "10.1016/j.ijhydene.2009.05.118",
language = "English",
volume = "34",
pages = "5683--5690",
journal = "International Journal of Hydrogen Energy",
issn = "0360-3199",
publisher = "Elsevier Limited",
number = "14",

}

RIS

TY - JOUR

T1 - Thermodynamic analysis of hydrogen production from glycerol autothermal reforming

AU - Wang, H.

AU - Wang, Xiaodong

AU - Li, M.

AU - Li, S.

AU - Wang, S.

AU - Ma, X.

PY - 2009

Y1 - 2009

N2 - In this work, thermodynamics was applied to investigate the glycerol autothermal reforming to generate hydrogen for fuel cell application. Equilibrium calculations employing the Gibbs free energy minimization were performed in a wide range of temperature (700–1000 K), steam to glycerol ratio (1–12) and oxygen to glycerol ratio (0.0–3.0). Results show that the most favorable conditions for hydrogen production are achieved with the temperatures, steam to glycerol ratios and oxygen to glycerol ratios of 900–1000 K, 9–12 and 0.0–0.4, respectively. Further, it is demonstrated that thermoneutral conditions (steam to glycerol ratio 9–12) can be obtained at oxygen to glycerol ratios of around 0.36 (at 900 K) and 0.38–0.39 (at 1000 K). Under these thermoneutral conditions, the maximum number of moles of hydrogen produced are 5.62 (900 K) and 5.43 (1000 K) with a steam to glycerol ratio of 12. Also, it should be noted that methane and carbon formation can be effectively eliminated.

AB - In this work, thermodynamics was applied to investigate the glycerol autothermal reforming to generate hydrogen for fuel cell application. Equilibrium calculations employing the Gibbs free energy minimization were performed in a wide range of temperature (700–1000 K), steam to glycerol ratio (1–12) and oxygen to glycerol ratio (0.0–3.0). Results show that the most favorable conditions for hydrogen production are achieved with the temperatures, steam to glycerol ratios and oxygen to glycerol ratios of 900–1000 K, 9–12 and 0.0–0.4, respectively. Further, it is demonstrated that thermoneutral conditions (steam to glycerol ratio 9–12) can be obtained at oxygen to glycerol ratios of around 0.36 (at 900 K) and 0.38–0.39 (at 1000 K). Under these thermoneutral conditions, the maximum number of moles of hydrogen produced are 5.62 (900 K) and 5.43 (1000 K) with a steam to glycerol ratio of 12. Also, it should be noted that methane and carbon formation can be effectively eliminated.

U2 - 10.1016/j.ijhydene.2009.05.118

DO - 10.1016/j.ijhydene.2009.05.118

M3 - Journal article

VL - 34

SP - 5683

EP - 5690

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

SN - 0360-3199

IS - 14

ER -