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Ti3AlC2 MAX phase as an efficient catalyst for oxidative dehydrogenation of n-butane

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Ti3AlC2 MAX phase as an efficient catalyst for oxidative dehydrogenation of n-butane. / Ng, Wesley H. K.; Gnanakumar, Edwin S.; Batyrev, Erdni et al.
In: Angewandte Chemie International Edition, Vol. 57, No. 6, 09.01.2018, p. 1485-1490.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Ng, WHK, Gnanakumar, ES, Batyrev, E, Sharma, SK, Pujari, PK, Greer, HF, Zhou, W, Sakidja, R, Rothenberg, G, Barsoum, MW & Raveendran, S 2018, 'Ti3AlC2 MAX phase as an efficient catalyst for oxidative dehydrogenation of n-butane', Angewandte Chemie International Edition, vol. 57, no. 6, pp. 1485-1490. https://doi.org/10.1002/anie.201702196

APA

Ng, W. H. K., Gnanakumar, E. S., Batyrev, E., Sharma, S. K., Pujari, P. K., Greer, H. F., Zhou, W., Sakidja, R., Rothenberg, G., Barsoum, M. W., & Raveendran, S. (2018). Ti3AlC2 MAX phase as an efficient catalyst for oxidative dehydrogenation of n-butane. Angewandte Chemie International Edition, 57(6), 1485-1490. https://doi.org/10.1002/anie.201702196

Vancouver

Ng WHK, Gnanakumar ES, Batyrev E, Sharma SK, Pujari PK, Greer HF et al. Ti3AlC2 MAX phase as an efficient catalyst for oxidative dehydrogenation of n-butane. Angewandte Chemie International Edition. 2018 Jan 9;57(6):1485-1490. doi: 10.1002/anie.201702196

Author

Ng, Wesley H. K. ; Gnanakumar, Edwin S. ; Batyrev, Erdni et al. / Ti3AlC2 MAX phase as an efficient catalyst for oxidative dehydrogenation of n-butane. In: Angewandte Chemie International Edition. 2018 ; Vol. 57, No. 6. pp. 1485-1490.

Bibtex

@article{87c3471767e0469b85f3a33ea7ae46d1,
title = "Ti3AlC2 MAX phase as an efficient catalyst for oxidative dehydrogenation of n-butane",
abstract = "Abstract Dehydrogenation or oxidative dehydrogenation (ODH) of alkanes to produce alkenes directly from natural gas/shale gas is gaining in importance. Ti3AlC2, a MAX phase, which hitherto had not been used in catalysis, efficiently catalyzes the ODH of n-butane to butenes and butadiene, which are important intermediates for the synthesis of polymers and other compounds. The catalyst, which combines both metallic and ceramic properties, is stable for at least 30?h on stream, even at low O2:butane ratios, without suffering from coking. This material has neither lattice oxygens nor noble metals, yet a unique combination of numerous defects and a thin surface Ti1?yAlyO2?y/2 layer that is rich in oxygen vacancies makes it an active catalyst. Given the large number of compositions available, MAX phases may find applications in several heterogeneously catalyzed reactions.",
author = "Ng, {Wesley H. K.} and Gnanakumar, {Edwin S.} and Erdni Batyrev and Sharma, {Sandeep K.} and Pujari, {Pradeep K.} and Greer, {Heather F.} and Wuzong Zhou and Ridwan Sakidja and Gadi Rothenberg and Barsoum, {Michel W.} and Shiju Raveendran",
year = "2018",
month = jan,
day = "9",
doi = "10.1002/anie.201702196",
language = "English",
volume = "57",
pages = "1485--1490",
journal = "Angewandte Chemie International Edition",
issn = "1433-7851",
publisher = "Wiley-VCH Verlag",
number = "6",

}

RIS

TY - JOUR

T1 - Ti3AlC2 MAX phase as an efficient catalyst for oxidative dehydrogenation of n-butane

AU - Ng, Wesley H. K.

AU - Gnanakumar, Edwin S.

AU - Batyrev, Erdni

AU - Sharma, Sandeep K.

AU - Pujari, Pradeep K.

AU - Greer, Heather F.

AU - Zhou, Wuzong

AU - Sakidja, Ridwan

AU - Rothenberg, Gadi

AU - Barsoum, Michel W.

AU - Raveendran, Shiju

PY - 2018/1/9

Y1 - 2018/1/9

N2 - Abstract Dehydrogenation or oxidative dehydrogenation (ODH) of alkanes to produce alkenes directly from natural gas/shale gas is gaining in importance. Ti3AlC2, a MAX phase, which hitherto had not been used in catalysis, efficiently catalyzes the ODH of n-butane to butenes and butadiene, which are important intermediates for the synthesis of polymers and other compounds. The catalyst, which combines both metallic and ceramic properties, is stable for at least 30?h on stream, even at low O2:butane ratios, without suffering from coking. This material has neither lattice oxygens nor noble metals, yet a unique combination of numerous defects and a thin surface Ti1?yAlyO2?y/2 layer that is rich in oxygen vacancies makes it an active catalyst. Given the large number of compositions available, MAX phases may find applications in several heterogeneously catalyzed reactions.

AB - Abstract Dehydrogenation or oxidative dehydrogenation (ODH) of alkanes to produce alkenes directly from natural gas/shale gas is gaining in importance. Ti3AlC2, a MAX phase, which hitherto had not been used in catalysis, efficiently catalyzes the ODH of n-butane to butenes and butadiene, which are important intermediates for the synthesis of polymers and other compounds. The catalyst, which combines both metallic and ceramic properties, is stable for at least 30?h on stream, even at low O2:butane ratios, without suffering from coking. This material has neither lattice oxygens nor noble metals, yet a unique combination of numerous defects and a thin surface Ti1?yAlyO2?y/2 layer that is rich in oxygen vacancies makes it an active catalyst. Given the large number of compositions available, MAX phases may find applications in several heterogeneously catalyzed reactions.

U2 - 10.1002/anie.201702196

DO - 10.1002/anie.201702196

M3 - Journal article

VL - 57

SP - 1485

EP - 1490

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

SN - 1433-7851

IS - 6

ER -