Final published version
Licence: CC BY: Creative Commons Attribution 4.0 International License
Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
}
TY - JOUR
T1 - Topological insights in polynuclear Ni/Na coordination clusters derived from a schiff base ligand
AU - Griffiths, Kieran
AU - Escuer, Albert
AU - Kostakis, George E.
PY - 2016/12/1
Y1 - 2016/12/1
N2 - This article presents the syntheses, crystal structures, topological features and magnetic properties of two NiII/NaI coordination clusters formulated [Ni3 IINa(L1)3(HL1)(MeOH)2] (1) and [Ni6 IINa(L1)5(CO3)(MeO)(MeOH)3(H2O)3]·4(MeOH) 2(H2O) [2 4(MeOH) 2(H2O)] where H2L1 is the semi-rigid Schiff base ligand (E)-2-(2-hydroxy-3-methoxybenzylideneamino)-phenol). Compound 1 possesses a rare Ni3 IINaI cubane (3M4-1) topology, and compound 2 is the first example in polynuclear Ni/Na chemistry that exhibits a 2,3,4M7-1 topology.
AB - This article presents the syntheses, crystal structures, topological features and magnetic properties of two NiII/NaI coordination clusters formulated [Ni3 IINa(L1)3(HL1)(MeOH)2] (1) and [Ni6 IINa(L1)5(CO3)(MeO)(MeOH)3(H2O)3]·4(MeOH) 2(H2O) [2 4(MeOH) 2(H2O)] where H2L1 is the semi-rigid Schiff base ligand (E)-2-(2-hydroxy-3-methoxybenzylideneamino)-phenol). Compound 1 possesses a rare Ni3 IINaI cubane (3M4-1) topology, and compound 2 is the first example in polynuclear Ni/Na chemistry that exhibits a 2,3,4M7-1 topology.
KW - Carbonate ion
KW - Coordination cluster
KW - Ferromagnetism
KW - Nickel
KW - Schiff base
KW - Sodium
KW - Topology
U2 - 10.1007/s11224-016-0797-7
DO - 10.1007/s11224-016-0797-7
M3 - Journal article
AN - SCOPUS:84981273188
VL - 27
SP - 1703
EP - 1714
JO - Structural Chemistry
JF - Structural Chemistry
SN - 1040-0400
IS - 6
ER -