Topological insights in polynuclear Ni/Na coordination clusters derived from a schiff base ligand

Chemistry

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https://doi.org/10.1007/s11224-016-0797-7
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Keywords

Carbonate ion, Coordination cluster, Ferromagnetism, Nickel, Schiff base, Sodium, Topology

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Topological insights in polynuclear Ni/Na coordination clusters derived from a schiff base ligand. / Griffiths, Kieran; Escuer, Albert; Kostakis, George E.
In: Structural Chemistry, Vol. 27, No. 6, 01.12.2016, p. 1703-1714.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Bibtex

@article{574e4a7f0a2844ec8eddd43fcb918e95,

title = "Topological insights in polynuclear Ni/Na coordination clusters derived from a schiff base ligand",

abstract = "This article presents the syntheses, crystal structures, topological features and magnetic properties of two NiII/NaI coordination clusters formulated [Ni3 IINa(L1)3(HL1)(MeOH)2] (1) and [Ni6 IINa(L1)5(CO3)(MeO)(MeOH)3(H2O)3]·4(MeOH) 2(H2O) [2 4(MeOH) 2(H2O)] where H2L1 is the semi-rigid Schiff base ligand (E)-2-(2-hydroxy-3-methoxybenzylideneamino)-phenol). Compound 1 possesses a rare Ni3 IINaI cubane (3M4-1) topology, and compound 2 is the first example in polynuclear Ni/Na chemistry that exhibits a 2,3,4M7-1 topology.",

keywords = "Carbonate ion, Coordination cluster, Ferromagnetism, Nickel, Schiff base, Sodium, Topology",

author = "Kieran Griffiths and Albert Escuer and Kostakis, {George E.}",

year = "2016",

month = dec,

day = "1",

doi = "10.1007/s11224-016-0797-7",

language = "English",

volume = "27",

pages = "1703--1714",

journal = "Structural Chemistry",

issn = "1040-0400",

publisher = "Springer New York",

number = "6",

}

RIS

TY - JOUR

T1 - Topological insights in polynuclear Ni/Na coordination clusters derived from a schiff base ligand

AU - Griffiths, Kieran

AU - Escuer, Albert

AU - Kostakis, George E.

PY - 2016/12/1

Y1 - 2016/12/1

N2 - This article presents the syntheses, crystal structures, topological features and magnetic properties of two NiII/NaI coordination clusters formulated [Ni3 IINa(L1)3(HL1)(MeOH)2] (1) and [Ni6 IINa(L1)5(CO3)(MeO)(MeOH)3(H2O)3]·4(MeOH) 2(H2O) [2 4(MeOH) 2(H2O)] where H2L1 is the semi-rigid Schiff base ligand (E)-2-(2-hydroxy-3-methoxybenzylideneamino)-phenol). Compound 1 possesses a rare Ni3 IINaI cubane (3M4-1) topology, and compound 2 is the first example in polynuclear Ni/Na chemistry that exhibits a 2,3,4M7-1 topology.

AB - This article presents the syntheses, crystal structures, topological features and magnetic properties of two NiII/NaI coordination clusters formulated [Ni3 IINa(L1)3(HL1)(MeOH)2] (1) and [Ni6 IINa(L1)5(CO3)(MeO)(MeOH)3(H2O)3]·4(MeOH) 2(H2O) [2 4(MeOH) 2(H2O)] where H2L1 is the semi-rigid Schiff base ligand (E)-2-(2-hydroxy-3-methoxybenzylideneamino)-phenol). Compound 1 possesses a rare Ni3 IINaI cubane (3M4-1) topology, and compound 2 is the first example in polynuclear Ni/Na chemistry that exhibits a 2,3,4M7-1 topology.

KW - Carbonate ion

KW - Coordination cluster

KW - Ferromagnetism

KW - Nickel

KW - Schiff base

KW - Sodium

KW - Topology

U2 - 10.1007/s11224-016-0797-7

DO - 10.1007/s11224-016-0797-7

M3 - Journal article

AN - SCOPUS:84981273188

VL - 27

SP - 1703

EP - 1714

JO - Structural Chemistry

JF - Structural Chemistry

SN - 1040-0400

IS - 6

ER -

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