Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
}
TY - JOUR
T1 - Topotactic elimination of water across a C-C ligand bond in a dense 3-D metal-organic framework
AU - Yeung, Hamish H. -M.
AU - Kosa, Monica
AU - Griffin, John M.
AU - Grey, Clare P.
AU - Major, Dan T.
AU - Cheetham, Anthony K.
AU - Griffin, John
PY - 2014/11/11
Y1 - 2014/11/11
N2 - Upon heating, lithium L-malate undergoes topotactic dehydration to form a phase containing the unsaturated fumarate ligand, in which the original 3-D framework remains intact. Insight into this unusual transformation has been obtained by single crystal X-ray diffraction, MAS-NMR, in situ powder X-ray diffraction and DFT calculations.
AB - Upon heating, lithium L-malate undergoes topotactic dehydration to form a phase containing the unsaturated fumarate ligand, in which the original 3-D framework remains intact. Insight into this unusual transformation has been obtained by single crystal X-ray diffraction, MAS-NMR, in situ powder X-ray diffraction and DFT calculations.
KW - COORDINATION POLYMERS
KW - STRUCTURAL TRANSFORMATIONS
KW - FLEXIBILITY
KW - DIVERSITY
KW - 2D
KW - 3D
U2 - 10.1039/c4cc06136e
DO - 10.1039/c4cc06136e
M3 - Journal article
VL - 50
SP - 13292
EP - 13295
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 87
ER -