Final published version
Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Vertical Distributions of Primary and Secondary Aerosols in Urban Boundary Layer
T2 - Insights into Sources, Chemistry, and Interaction with Meteorology
AU - Lei, L.
AU - Sun, Y.
AU - Ouyang, B.
AU - Qiu, Y.
AU - Xie, C.
AU - Tang, G.
AU - Zhou, W.
AU - He, Y.
AU - Wang, Q.
AU - Cheng, X.
AU - Fu, P.
AU - Wang, Z.
PY - 2021/4/20
Y1 - 2021/4/20
N2 - Vertical measurements are essential for the characterization of aerosol and boundary layer interactions; yet, our knowledge of vertical profiles of primary and secondary aerosol species in megacities is limited. Here, we conducted comprehensive vertical measurements of aerosol particle composition on a 325 m meteorological tower with two aerosol chemical speciation monitors in winter in urban Beijing. The simultaneous measurements at ground level, 140, and 240 m illustrated similar aerosol bulk composition at these three heights. However, the vertical ratios varied significantly among different aerosol species. Particularly, the vertical ratios of the aqueous phase and photochemical-related secondary organic aerosol (SOA) (aqOOA/OOA) decreased significantly, accompanied by the increases in ratios of secondary to primary OA, highlighting different chemical properties of OA between ground level and aloft, and the large impacts of vertical changes in meteorology and gaseous precursors on SOA formation. The vertical changes in NO3/SO4 ratios, however, were mostly insignificant, likely due to the low relative humidity and aerosol water content that inhibited nocturnal heterogeneous reactions in the residual layer. Considerable increases in the ratios of 240 m to ground level in the early morning were also observed for most aerosol species, demonstrating impact of residual layer on the air pollution of 2nd day.
AB - Vertical measurements are essential for the characterization of aerosol and boundary layer interactions; yet, our knowledge of vertical profiles of primary and secondary aerosol species in megacities is limited. Here, we conducted comprehensive vertical measurements of aerosol particle composition on a 325 m meteorological tower with two aerosol chemical speciation monitors in winter in urban Beijing. The simultaneous measurements at ground level, 140, and 240 m illustrated similar aerosol bulk composition at these three heights. However, the vertical ratios varied significantly among different aerosol species. Particularly, the vertical ratios of the aqueous phase and photochemical-related secondary organic aerosol (SOA) (aqOOA/OOA) decreased significantly, accompanied by the increases in ratios of secondary to primary OA, highlighting different chemical properties of OA between ground level and aloft, and the large impacts of vertical changes in meteorology and gaseous precursors on SOA formation. The vertical changes in NO3/SO4 ratios, however, were mostly insignificant, likely due to the low relative humidity and aerosol water content that inhibited nocturnal heterogeneous reactions in the residual layer. Considerable increases in the ratios of 240 m to ground level in the early morning were also observed for most aerosol species, demonstrating impact of residual layer on the air pollution of 2nd day.
KW - Aerosols
KW - Boundary layer flow
KW - Boundary layers
KW - Chemical speciation
KW - Meteorological instruments
KW - Meteorology
KW - Aerosol-particle composition
KW - Boundary layer interaction
KW - Heterogeneous reactions
KW - Low relative humidities
KW - Secondary organic aerosols
KW - Simultaneous measurement
KW - Urban boundary layers
KW - Vertical distributions
KW - Air pollution
U2 - 10.1021/acs.est.1c00479
DO - 10.1021/acs.est.1c00479
M3 - Journal article
VL - 55
SP - 4542
EP - 4552
JO - Environmental Science and Technology
JF - Environmental Science and Technology
SN - 0013-936X
IS - 8
ER -