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    Rights statement: © 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.

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Yttrium complexes of Arsine, Arsenide, and Arsinidene Ligands

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Yttrium complexes of Arsine, Arsenide, and Arsinidene Ligands. / Pugh, Thomas; Kerridge, Andrew; Layfield, Richard.

In: Angewandte Chemie International Edition, Vol. 54, No. 14, 27.03.2015, p. 4255-4258.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

Harvard

Pugh, T, Kerridge, A & Layfield, R 2015, 'Yttrium complexes of Arsine, Arsenide, and Arsinidene Ligands', Angewandte Chemie International Edition, vol. 54, no. 14, pp. 4255-4258. https://doi.org/10.1002/anie.201500173

APA

Pugh, T., Kerridge, A., & Layfield, R. (2015). Yttrium complexes of Arsine, Arsenide, and Arsinidene Ligands. Angewandte Chemie International Edition, 54(14), 4255-4258. https://doi.org/10.1002/anie.201500173

Vancouver

Pugh T, Kerridge A, Layfield R. Yttrium complexes of Arsine, Arsenide, and Arsinidene Ligands. Angewandte Chemie International Edition. 2015 Mar 27;54(14):4255-4258. https://doi.org/10.1002/anie.201500173

Author

Pugh, Thomas ; Kerridge, Andrew ; Layfield, Richard. / Yttrium complexes of Arsine, Arsenide, and Arsinidene Ligands. In: Angewandte Chemie International Edition. 2015 ; Vol. 54, No. 14. pp. 4255-4258.

Bibtex

@article{d810a07f669140baad2eadefd1ebaced,
title = "Yttrium complexes of Arsine, Arsenide, and Arsinidene Ligands",
abstract = "Deprotonation of the yttrium–arsine complex [Cp′3Y{As(H)2Mes}] (1) (Cp′=η5-C5H4Me, Mes=mesityl) by nBuLi produces the μ-arsenide complex [{Cp′2Y[μ-As(H)Mes]}3] (2). Deprotonation of the As[BOND]H bonds in 2 by nBuLi produces [Li(thf)4]2[{Cp′2Y(μ3-AsMes)}3Li], [Li(thf)4]2[3], in which the dianion 3 contains the first example of an arsinidene ligand in rare-earth metal chemistry. The molecular structures of the arsine, arsenide, and arsinidene complexes are described, and the yttrium–arsenic bonding is analyzed by density functional theory.",
keywords = "arsenic, arsinidene ligands, lithium, rare-earth elements, yttrium",
author = "Thomas Pugh and Andrew Kerridge and Richard Layfield",
note = "{\textcopyright} 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.",
year = "2015",
month = mar,
day = "27",
doi = "10.1002/anie.201500173",
language = "English",
volume = "54",
pages = "4255--4258",
journal = "Angewandte Chemie International Edition",
issn = "1433-7851",
publisher = "Wiley-VCH Verlag",
number = "14",

}

RIS

TY - JOUR

T1 - Yttrium complexes of Arsine, Arsenide, and Arsinidene Ligands

AU - Pugh, Thomas

AU - Kerridge, Andrew

AU - Layfield, Richard

N1 - © 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.

PY - 2015/3/27

Y1 - 2015/3/27

N2 - Deprotonation of the yttrium–arsine complex [Cp′3Y{As(H)2Mes}] (1) (Cp′=η5-C5H4Me, Mes=mesityl) by nBuLi produces the μ-arsenide complex [{Cp′2Y[μ-As(H)Mes]}3] (2). Deprotonation of the As[BOND]H bonds in 2 by nBuLi produces [Li(thf)4]2[{Cp′2Y(μ3-AsMes)}3Li], [Li(thf)4]2[3], in which the dianion 3 contains the first example of an arsinidene ligand in rare-earth metal chemistry. The molecular structures of the arsine, arsenide, and arsinidene complexes are described, and the yttrium–arsenic bonding is analyzed by density functional theory.

AB - Deprotonation of the yttrium–arsine complex [Cp′3Y{As(H)2Mes}] (1) (Cp′=η5-C5H4Me, Mes=mesityl) by nBuLi produces the μ-arsenide complex [{Cp′2Y[μ-As(H)Mes]}3] (2). Deprotonation of the As[BOND]H bonds in 2 by nBuLi produces [Li(thf)4]2[{Cp′2Y(μ3-AsMes)}3Li], [Li(thf)4]2[3], in which the dianion 3 contains the first example of an arsinidene ligand in rare-earth metal chemistry. The molecular structures of the arsine, arsenide, and arsinidene complexes are described, and the yttrium–arsenic bonding is analyzed by density functional theory.

KW - arsenic

KW - arsinidene ligands

KW - lithium

KW - rare-earth elements

KW - yttrium

U2 - 10.1002/anie.201500173

DO - 10.1002/anie.201500173

M3 - Journal article

VL - 54

SP - 4255

EP - 4258

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

SN - 1433-7851

IS - 14

ER -