We have over 12,000 students, from over 100 countries, within one of the safest campuses in the UK


93% of Lancaster students go into work or further study within six months of graduating

Home > Research > Publications & Outputs > Streamflow and hydrogen ion interrelationships ...
View graph of relations

« Back

Streamflow and hydrogen ion interrelationships identified using data-based mechanistic modelling of high frequency observations through contiguous storms.

Research output: Contribution to journalJournal article


Journal publication date2014
JournalHydrology Research
Number of pages25
Early online date7/04/14
Original languageEnglish


With the aim of quantifying the purely hydrological control on fast water quality dynamics, a modelling approach was used to identify the structure (and dynamic response characteristics or DRCs) of the relationship between rainfall and hydrogen ion (H+) load, with reference to rainfall to streamflow response. Unlike most hydrochemistry studies, the method used makes no a priori assumptions about the complexity of the dynamics (e.g., number of flow-paths), but instead uses objective statistical methods to define these (together with uncertainty analysis). The robust models identified are based on continuous-time transfer functions and demonstrate high simulation efficiency with a constrained uncertainty allowing hydrological interpretation of dominant flow-paths and behaviour of H+ load in four upland headwaters. Identified models demonstrated that the short-term dynamics in H+ concentration were closely associated with the streamflow response, suggesting a dominant hydrological control. The second-order structure identified for the rainfall to streamflow response was also seen as the optimal models for rainfall to H+ load, even given the very dynamic concentration response, possibly indicating the same two flow-paths being responsible for both integrated responses.

Related projects